Secondary bonding as a potential design element for crystal engineering

被引:112
作者
Starbuck, J [1 ]
Norman, NC [1 ]
Orpen, AG [1 ]
机构
[1] Univ Bristol, Sch Chem, Bristol BS8 1TS, Avon, England
关键词
D O I
10.1039/a906352h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Crystallographic data imply that intermolecular hypervalent interactions, "secondary bonds", involving heavy p-block elements such as Bi(III), may form robust supramolecular synthons with many features in common with organic hydrogen bonds, including the ability to form polymeric networks in the solid state.
引用
收藏
页码:969 / 972
页数:4
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