On the distinction between radical chemistry and gif chemistry

被引：17
作者：
Barton, DHR
Launay, F
LeGloahec, VN
Li, TS
Smith, F
机构：
[1] Department of Chemistry, Texas A and M University, College Station
来源：
TETRAHEDRON LETTERS | 1997年 / 38卷 / 49期
关键词：
D O I：
10.1016/S0040-4039(97)10308-2
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Normalized data for cyclooctane and for cyclododecane are compared with cyclohexane as unity. In radical chemistry cyclooctane is 2-3 times more reactive per hydrogen, whereas in Gif chemistry cyclohexane is more reactive than cyclooctane or cyclododecane. Thus by simple competitive experiments a distinction between radical chemistry and Gif chemistry can be made. (C) 1997 Elsevier Science Ltd.
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收藏
页码：8491 / 8494
页数：4
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