Heterogeneous asymmetric epoxidation of alkenes catalysed by a polymer-bound (pyrrolidine salen)manganese(III) complex

被引：108
作者：
Song, CE
Roh, EJ
Yu, BM
Chi, DY
Kim, SC
Lee, KJ
机构：
[1] Korea Inst Sci & Technol, Div Life Sci, Seoul 130650, South Korea
[2] Inha Univ, Dept Chem, Inchon 402751, South Korea
[3] Hanyang Univ, Div Chem Engn & Ind Chem, Seoul 133791, South Korea
来源：
CHEMICAL COMMUNICATIONS | 2000年 / 07期
关键词：
D O I：
10.1039/b000876l
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Excellent enantioselectivity (e.g. 92% ee for 2,2-dimethylchromene) has been achieved in heterogeneous asymmetric epoxidation using a polymer-bound (pyrrolidine salen)-manganese(III) complex; however, this polymeric catalyst underwent partial decomposition under epoxidation conditions.
引用
收藏
页码：615 / 616
页数：2
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