Oxygen gas, O2(g), by near-ambient pressure XPS

被引:24
作者
Avval, Tahereh G. [1 ]
Chatterjee, Shiladitya [1 ]
Hodges, Grant T. [1 ]
Bahr, Stephan [2 ]
Dietrich, Paul [2 ]
Meyer, Michael [2 ]
Thissen, Andreas [2 ]
Linford, Matthew R. [1 ]
机构
[1] Brigham Young Univ, Dept Chem & Biochem, C100 BNSN, Provo, UT 84602 USA
[2] SPECS Surface Nano Anal GmbH, Voltastr 5, D-13355 Berlin, Germany
来源
SURFACE SCIENCE SPECTRA | 2019年 / 26卷 / 01期
关键词
near-ambient pressure x-ray photoelectron spectroscopy; NAP-XPS; XPS; oxygen; O-2(g); PHOTOELECTRON-SPECTROSCOPY;
D O I
10.1116/1.5100962
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
Near-ambient pressure x-ray photoelectron spectroscopy (NAP-XPS) is a less traditional form of XPS that allows samples to be analyzed at relatively high pressures, i.e., greater than 2500Pa. With NAP-XPS, XPS can probe moderately volatile liquids, biological samples, porous materials, and/or polymeric materials that outgas significantly. In this submission, we show the survey, O 1s, valence band, and O KLL Auger NAP-XPS spectra of oxygen gas, O-2, a material that would be difficult to analyze by conventional XPS. A small N 1s signal from N-2(g) is also observed in the survey spectrum. The O 1s narrow scan is fit to Gaussian-Lorentzian sum functions. The Lorentzian character of this synthetic line shape was varied to obtain the best fit. Since it is likely that O-2(g) will be present in other NAP-XPS analyses, these data should serve as a useful reference for other researchers. Published by the AVS.
引用
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页数:6
相关论文
共 17 条
[1]  
Allan C. J., 1972, Journal of Electron Spectroscopy and Related Phenomena, V1, P131, DOI 10.1016/0368-2048(72)80027-6
[2]   Carbon dioxide gas, CO2(g), by near-ambient pressure XPS [J].
Avval, Tahereh G. ;
Chatterjee, Shiladitya ;
Bahr, Stephan ;
Dietrich, Paul ;
Meyer, Michael ;
Thissen, Andreas ;
Linford, Matthew R. .
SURFACE SCIENCE SPECTRA, 2019, 26 (01)
[3]   XPS STUDIES OF THE OXYGEN-1S AND OXYGEN-2S LEVELS IN A WIDE-RANGE OF FUNCTIONAL POLYMERS [J].
BRIGGS, D ;
BEAMSON, G .
ANALYTICAL CHEMISTRY, 1993, 65 (11) :1517-1523
[4]   O-2 on ganymede: Spectral characteristics and plasma formation mechanisms [J].
Calvin, WM ;
Johnson, RE ;
Spencer, JR .
GEOPHYSICAL RESEARCH LETTERS, 1996, 23 (06) :673-676
[5]   Chemical surface analysis on materials and devices under functional conditions - Environmental photoelectron spectroscopy as non-destructive tool for routine characterization [J].
Dietrich, Paul M. ;
Bahr, Stephan ;
Yamamoto, Takashi ;
Meyer, Michael ;
Thissen, Andreas .
JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA, 2019, 231 :118-126
[6]   ENERGY SPLITTING OF CORE ELECTRON LEVELS IN PARAMAGNETIC MOLECULES [J].
HEDMAN, J ;
HEDEN, PF ;
NORDLING, C ;
SIEGBAHN, K .
PHYSICS LETTERS A, 1969, A 29 (04) :178-&
[7]   The Gaussian-Lorentzian Sum, Product, and Convolution (Voigt) functions in the context of peak fitting X-ray photoelectron spectroscopy (XPS) narrow scans [J].
Jain, Varun ;
Biesinger, Mark C. ;
Linford, Matthew R. .
APPLIED SURFACE SCIENCE, 2018, 447 :548-553
[8]   Surface characterisation of Escherichia coli under various conditions by near-ambient pressure XPS [J].
Kjaervik, Marit ;
Schwibbert, Karin ;
Dietrich, Paul ;
Thissen, Andreas ;
Unger, Wolfgang E. S. .
SURFACE AND INTERFACE ANALYSIS, 2018, 50 (11) :996-1000
[9]   Water vapor, by near-ambient pressure XPS [J].
Patel, Dhananjay I. ;
Shah, Dhruv ;
Bahr, Stephan ;
Dietrich, Paul ;
Meyer, Michael ;
Thissen, Andreas ;
Linford, Matthew R. .
SURFACE SCIENCE SPECTRA, 2019, 26 (01)
[10]   Argon gas, by near-ambient pressure XPS [J].
Patel, Dhananjay I. ;
Bahr, Stephan ;
Dietrich, Paul ;
Meyer, Michael ;
Thissen, Andreas ;
Linford, Matthew R. .
SURFACE SCIENCE SPECTRA, 2019, 26 (01)