Syntheses and optical characterization of poly[1,8-octanedioxy-1,4-phenylene-1,2-ethylene-1,4-phenylene] and its copolymer derivatives

被引：6

作者：

Cho, IH ^{[1
]}

Oh, EJ

Suh, JS

Park, SJ

Lee, KW

机构：

[1] Myongji Univ, Nat Sci Res Inst, Yongin 449728, Kyonggi, South Korea

[2] Myongji Univ, Dept Chem, Yongin 449728, Kyonggi, South Korea

[3] Myongji Univ, Elect Mat Res Ctr, Yongin 449728, Kyonggi, South Korea

来源：

THIN SOLID FILMS | 2000年 / 363卷 / 1-2期

关键词：

PPV copolymer; blue emission; pi conjugation; methoxy derivatives;

D O I：

10.1016/S0040-6090(99)01022-6

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

We have investigated the optical properties of a series of poly(p-phenylene vinylene) (PPV) copolymers. Three-wide bandgap PPV copolymers were synthesized and characterized. The new PPV copolymers showed a large blue shift in both absorption and emission that their average bandgap is over 3.1 eV. A significant solvatochromic effect was observed in the photoluminescence (PL) spectra of copolymers. The dimethoxy-substituted copolymer showed the highest quantum efficiency and processability among three copolymers. (C) 2000 Elsevier Science S.A. All rights reserved.

引用

页码：138 / 142

页数：5