Crystal structures and photoluminescent properties of two d10 metal coordination polymers based on 5-aminodiacetic isophthalic acid

被引：7
作者：
Zhang, Lingling [1 ]
Wang, Xiubo [1 ]
Hu, Ming [1 ]
机构：
[1] Inner Mongolia Univ, Inner Mongolia Key Lab Chem & Phys Rare Earth Mat, Sch Chem & Chem Engn, Hohhot 010021, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2014年 / 45卷
基金：
中国国家自然科学基金;
关键词：
Transition metal; Coordination polymer; Crystal structure; Photoluminescence; ORGANIC FRAMEWORKS; LIGANDS; COMPLEXES; SERIES; TEMPERATURE; TOPOLOGIES; SOLVENT; MOF;
D O I：
10.1016/j.inoche.2014.04.009
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Based on the 5-aminodiacetic isophthalic acid (H(4)adip), two novel luminescent d(10) metal coordination polymers have been successfully synthesized under hydrothermal conditions, namely, [Zn-2.5(mu(2)-OH)(adip)(H2O)(2)center dot 3H(2)O (1), [Cd-2(adip) (H2O)(4)]center dot 2H(2)O (2). Compound 1 is a two-dimensional network structure based on the metal five-nuclear subunits. It is extraordinary that 2 is a three-dimensional structure containing two different kinds of pores, the dimensions of the pores are 11.46 x 11.13 angstrom and 11.43 x 7.49 angstrom, respectively. The photoluminescent properties of 1-2 were further investigated. (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码：75 / 78
页数：4
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