A fluorescent and colorimetric chemosensor for selective detection of aluminum in aqueous solution

被引：70
作者：
Kim, Kyung Beom [1 ,2 ]
You, Dong Min [3 ]
Jeon, Jun Hwi [3 ]
Yeon, Yo Han [3 ]
Kim, Jong Ha [3 ]
Kim, Cheal [1 ,2 ]
机构：
[1] Seoul Natl Univ Sci & Technol, Dept Fine Chem, Seoul 139743, South Korea
[2] Seoul Natl Univ Sci & Technol, Dept Interdisciplinary Bio IT Mat, Seoul 139743, South Korea
[3] Sejong Sci High Sch, Seoul 152881, South Korea
来源：
TETRAHEDRON LETTERS | 2014年 / 55卷 / 07期
基金：
新加坡国家研究基金会;
关键词：
Fluorogenic; Chromogenic; Chemosensor; Schiff base; Aluminum; NAKED-EYE DETECTION; TURN-ON; CHROMOGENIC CHEMOSENSOR; AL3+ IONS; SENSOR; PROBE; RHODAMINE; CU2+; HG2+; DERIVATIVES;
D O I：
10.1016/j.tetlet.2014.01.021
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
We have synthesized a new Schiff base 1, which detects Al3+ through fluorescence and naked eye in aqueous solution. The sensor 1 exhibited selective and sensitive recognition toward Al3+ via significant fluorescence enhancement (31-fold). Moreover, it showed a significant color change from colorless to yellow. The complex formation was proposed to be 1:1 ratio, based on the Job plot, ESI-mass spectrometry analysis, H-1 NMR titration, and IR analysis. The detection limit was 1.00 mu M, which is below the WHO acceptable limit (1.85 mu M) in drinking water. In addition, the sensor 1 could be recyclable simply through treatment with a proper reagent such as EDTA. (C) 2014 Elsevier Ltd. All rights reserved.
引用
收藏
页码：1347 / 1352
页数：6
相关论文
共 72 条
[1]  
Andrási E, 2005, J ALZHEIMERS DIS, V7, P273
[2]   Fast root growth responses, root exudates, and internal detoxification as clues to the mechanisms of aluminium toxicity and resistance: a review [J].
Barcelo, J ;
Poschenrieder, C .
ENVIRONMENTAL AND EXPERIMENTAL BOTANY, 2002, 48 (01) :75-92
[3]   Colorimetric detection of Cu[II] cation and acetate, benzoate, and cyanide anions by cooperative receptor binding in new α,α′-bis-substituted donor-acceptor ferrocene sensors [J].
Basurto, Sara ;
Riant, Olivier ;
Moreno, Daniel ;
Rojo, Josefa ;
Torroba, Tomas .
JOURNAL OF ORGANIC CHEMISTRY, 2007, 72 (13) :4673-4688
[4]   A novel benzothiazole based azocalix[4]arene as a highly selective chromogenic chemosensor for Hg2+ ion: A rapid test application in aqueous environment [J].
Bingol, Haluk ;
Kocabas, Erdal ;
Zor, Erhan ;
Coskun, Ahmet .
TALANTA, 2010, 82 (04) :1538-1542
[5]   A turn-on and reversible Schiff base fluorescence sensor for Al3+ ion [J].
Chen, Chang-Hung ;
Liao, De-Jhong ;
Wan, Chin-Feng ;
Wu, An-Tai .
ANALYST, 2013, 138 (09) :2527-2530
[6]   Hg2+ Selective Fluorescent and Colorimetric Sensor: Its Crystal Structure and Application to Bioimaging [J].
Chen, Xiaoqiang ;
Nam, Seong-Won ;
Jou, Min Jung ;
Kim, Youngmee ;
Kim, Sung-Jin ;
Park, Sungsu ;
Yoon, Juyoung .
ORGANIC LETTERS, 2008, 10 (22) :5235-5238
[7]   New fluorescent and colorimetric chemosensors bearing rhodamine and binaphthyl groups for the detection of Cu2+ [J].
Chen, Xiaoqiang ;
Jou, Min Jung ;
Lee, Hanyoung ;
Kou, Songzi ;
Lim, Jeesun ;
Nam, Seong-Won ;
Park, Sungsu ;
Kim, Kwan-Mook ;
Yoon, Juyoung .
SENSORS AND ACTUATORS B-CHEMICAL, 2009, 137 (02) :597-602
[8]   A pyridinyl-functionalized tetraphenylethylene fluorogen for specific sensing of trivalent cations [J].
Chen, Xiujuan ;
Shen, Xiao Yuan ;
Guan, Erjia ;
Liu, Yi ;
Qin, Anjun ;
Sun, Jing Zhi ;
Tang, Ben Zhong .
CHEMICAL COMMUNICATIONS, 2013, 49 (15) :1503-1505
[9]   A highly selective "turn-on" fluorescent chemosensor based on hydroxy pyrene-hydrazone derivative for Zn2+ [J].
Choi, Ji Young ;
Kim, Dabin ;
Yoon, Juyoung .
DYES AND PIGMENTS, 2013, 96 (01) :176-179
[10]   Ratiometric fluorescence sensing and intracellular imaging of Al3+ ions driven by an intramolecular excimer formation of a pyrimidine-pyrene scaffold [J].
Das, Sudipta ;
Sahana, Animesh ;
Banerjee, Arnab ;
Lohar, Sisir ;
Safin, Damir A. ;
Babashkina, Maria G. ;
Bolte, Michael ;
Garcia, Yann ;
Hauli, Ipsit ;
Mukhopadhyay, Subhra Kanti ;
Das, Debasis .
DALTON TRANSACTIONS, 2013, 42 (14) :4757-4763
12345678