Electrofluorochromism in π-conjugated ionic liquid crystals

被引：152

作者：

Beneduci, Amerigo ^{[1
]}

Cospito, Sante ^{[1
]}

La Deda, Massimo ^{[1
]}

Veltri, Lucia ^{[1
]}

Chidichimo, Giuseppe ^{[1
]}

机构：

[1] Univ Calabria, Dept Chem & Chem Technol, I-87036 Arcavacata Di Rende, CS, Italy

来源：

NATURE COMMUNICATIONS | 2014年 / 5卷

关键词：

ELECTROCHEMICALLY CONVERTIBLE YELLOW; PHOTOLUMINESCENCE QUANTUM YIELDS; FLUORESCENCE; LUMINESCENCE; MODULATION; MICROSCOPY; FERROCENE; COLUMNAR; COMPLEX;

D O I：

10.1038/ncomms4105

中图分类号：

O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];

学科分类号：

07 ; 0710 ; 09 ;

摘要：

Materials in which photoluminescence is modulated by redox processes are known as electrofluorochromic. Intrinsically switchable fluorophores, incorporating both redox and fluorescent moieties, could be ideal electrofluorochromic materials if they possess high fluorescence quantum yields in at least one of their redox states. Fluorescent liquid crystals with redox active centres could combine the above requirements with the advantage to work in bulk anisotropic phases. However, electrofluorochromic liquid crystals have not been reported yet because their synthesis is challenging due to aggregation-caused fluorescent quenching. Here we show the first examples of electrofluorochromic pi-conjugated ionic liquid crystals based on thienoviologens. These ordered materials, combining ionic and electronic functions, are highly fluorescence in the bulk state (quantum yield >60%). Their direct electrochemical reduction leads to fast and reversible bulk electrofluorochromic response in both columnar and smectic phases allowing for fluorescence intensity modulation and colour tuning.

引用

页数：8

共 36 条

[1] Experimental and theoretical characterization of a new synthesized extended viologen [J].