Phosphorylated ordered mesoporous carbon as a novel solid acid catalyst for the esterification of oleic acid

被引：30

作者：

Wang, Lingtao ^{[1
]}

Dong, Xiuqin ^{[1
]}

Jiang, Haoxi ^{[1
]}

Li, Guiming ^{[1
]}

Zhang, Minhua ^{[1
]}

机构：

[1] Tianjin Univ, Key Lab Green Chem Technol, Minist Educ, Res & Dev Ctr Petrochem Technol, Tianjin 300072, Peoples R China

来源：

CATALYSIS COMMUNICATIONS | 2014年 / 56卷

基金：

中国国家自然科学基金;

关键词：

Ordered mesoporous carbon (OMC); Phosphorylation; Solid acid catalyst; Esterification; Oleic acid; WASTE COOKING OIL; ACTIVATED CARBON; BIODIESEL PRODUCTION; COMPOSITES;

D O I：

10.1016/j.catcom.2014.07.008

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A novel phosphorylated ordered mesoporous carbon (POMC) solid acid catalyst has been prepared by modifying mesoporous carbon with phosphoric acid, and was employed to catalyze the esterification oleic acid with methanol. The effects of the carbonization temperature on the type of phosphorus species formed, the phosphorus content and the amount of acid in the POMC were investigated. A mechanism for the phosphorylation of the ordered mesoporous carbon is proposed. The POMCs have good catalytic activity for the esterification of oleic acid and showed good reusability. (C) 2014 Elsevier B.V. All rights reserved.

引用

页码：164 / 167

页数：4

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