Hyper-Cross-Linked Polymer on the Hollow Conjugated Microporous Polymer Platform: A Heterogeneous Catalytic System for Poly(caprolactone) Synthesis

被引:32
作者
Choi, Sung Jae [1 ]
Choi, Eun Ho [1 ]
Song, Changsik [1 ]
Ko, Yoon-Joo [1 ,2 ]
Lee, Sang Moon [3 ]
Kim, Hae Jin [3 ]
Jang, Hye-Young [4 ]
Son, Seung Uk [1 ]
机构
[1] Sungkyunkwan Univ, Dept Chem, Suwon 16419, South Korea
[2] Seoul Natl Univ, Lab Nucl Magnet Resonance, NCIRF, Seoul 08826, South Korea
[3] Korea Basic Sci Inst, Daejeon 34133, South Korea
[4] Ajou Univ, Dept Energy Syst Res, Suwon 16499, South Korea
基金
新加坡国家研究基金会;
关键词
RING-OPENING POLYMERIZATION; CARBON-DIOXIDE CAPTURE; HYPERCROSSLINKED POLYMERS; ORGANIC POLYMERS; BRONSTED ACID; SURFACE-AREA; NETWORKS; DESIGN; IMIDAZOLIUM; TEMPLATES;
D O I
10.1021/acsmacrolett.9b00229
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
This work shows that the shape-controlled microporous organic polymer (MOP) can be utilized for the morphological engineering of another class of MOP materials. The morphology of a hyper-cross-linked polymer (HCP) was successfully engineered on the hollow conjugated microporous polymer (CMP). Through the postsynthetic modification of HCP bearing BINOLs (HCP-B) on the hollow CMP-like material (H-CMPL), the HCP bearing BINOL phosphoric acid (HCP-BP) was engineered on the H-CMPL platform. The resultant H-CMPL@HCP-BP showed good catalytic performance as a heterogeneous catalytic system and excellent recyclability in the ring-opening polymerization of epsilon-caprolactones to poly(caprolactone).
引用
收藏
页码:687 / 693
页数:13
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