A Unique (3,3,4)-Connected CdII Coordination Polymer with Dicarboxylate and Imidazole-Containing Coligands: Synthesis, Crystal Structure, and Luminescent Property

被引：2

作者：

Jia, Huali ^{[1
]}

Wang, Chunjie ^{[1
]}

Guo, Feng ^{[2
]}

机构：

[1] Zhoukou Normal Univ, Coll Chem & Chem Engn, Zhoukou 466001, Peoples R China

[2] Dezhou Univ, Key Lab Coordinat Chem & Funct Mat Univ Shandong, Dezhou 253023, Peoples R China

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2014年 / 640卷 / 12-13期

关键词：

Crystal structure; Cadmium; Coordination polymer; Luminescence; METAL-ORGANIC FRAMEWORKS; LIGAND; TOPOLOGIES; NETWORK; DESIGN; CO2;

D O I：

10.1002/zaac.201400294

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The three-dimensional (3D) coordination polymer {[Cd-2(4,4'-sdb)(2)(tib)(H2O)(3)]center dot H2O}(n) (1) [4,4'-H(2)sdb = 4,4'-sulfonyldicarboxylic acid and tib = 1,3,5,-tris(1-imidazolyl) benzene] was prepared by the combination of a V-shaped 4,4'-sulfonyl-dicarboxylic acid and neutral organonitrogen coligands. The structure of the neutral polymeric complex 1 was determined by single-crystal X-ray diffraction studies. Complex 1 exhibits a twofold interpenetrated (3,3,4)-connected 3D architecture with the point symbol (6.8(2)).(6(4).8(2)).(8(3)). In addition, the luminescent property of complex 1 was investigated.

引用

页码：2508 / 2511

页数：4

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