Copper-catalyzed phosphorylation of sp2 C-H bonds

被引：63

作者：

Wang, Shan ^{[1
]}

Guo, Rui ^{[1
]}

Wang, Gao ^{[1
]}

Chen, Shan-Yong ^{[1
]}

Yu, Xiao-Qi ^{[1
]}

机构：

[1] Sichuan Univ, Coll Chem, Key Lab Green Chem & Technol, Minist Educ, Chengdu 610064, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 84期

基金：

美国国家科学基金会;

关键词：

CROSS-COUPLING REACTIONS; ASYMMETRIC CATALYSIS; C(SP(3))-H BONDS; DIRECT ARYLATION; GENERAL-METHOD; ARENE; PHOSPHONATION; AMINATION; FUNCTIONALIZATION; PHOSPHINES;

D O I：

10.1039/c4cc06246a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The phosphorylation of the ortho C-H bonds in benzamides containing an 8-aminoquinoline moiety as a bidentate directing group with H-phosphonates using copper as a catalyst under mild temperature conditions is described. This method shows high functional group compatibility and selectively gives mono-substituted products.

引用

页码：12718 / 12721

页数：4

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