Decomposition of hydrazine by an organic fullerene-phthalocyanine p-n bilayer photocatalysis system over the entire visible-light region

被引：38
作者：
Abe, Toshiyuki [1 ]
Taira, Naohiro [1 ]
Tanno, Yoshinori [1 ]
Kikuchi, Yuko [1 ]
Nagai, Keiji [2 ]
机构：
[1] Hirosaki Univ, Grad Sch Sci & Technol, Dept Frontier Mat Chem, Hirosaki, Aomori 0368561, Japan
[2] Tokyo Inst Technol, Chem Resources Lab, Midori Ku, Yokohama, Kanagawa 2268503, Japan
来源：
CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 16期
关键词：
HYDROGEN EVOLUTION; FULL-SPECTRUM; P/N BILAYER; WATER PHASE; NITROGEN; WORKING; FILM;
D O I：
10.1039/c3cc46701e
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
An organic p-n bilayer photocatalysis system successfully induced the oxidative decomposition of hydrazine (N2H4) into N-2 and simultaneously yielded H-2 from H+. This demonstrates the first instance of the stoichiometric decomposition of N2H4 under visible-light irradiation.
引用
收藏
页码：1950 / 1952
页数：3
相关论文
共 24 条
  • [1] Robust dye-sensitized overall water splitting system with two-step photoexcitation of coumarin dyes and metal oxide semiconductors
    Abe, Ryu
    Shinmei, Kenichi
    Hara, Kohjiro
    Ohtani, Bunsho
    [J]. CHEMICAL COMMUNICATIONS, 2009, (24) : 3577 - 3579
  • [2] An organic photoelectrode working in the water phase: Visible-light-induced dioxygen evolution by a perylene derivative/cobalt phthalocyanine bilayer
    Abe, T
    Nagai, K
    Kabutomori, S
    Kaneko, M
    Tajiri, A
    Noritnatsit, T
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (17) : 2778 - 2781
  • [3] Novel and efficient system of a visible-light-responsive organic photoelectrocatalyst working in a water phase
    Abe, T
    Nagai, K
    Kaneko, M
    Okubo, T
    Sekimoto, K
    Tajiri, A
    Norimatsu, T
    [J]. CHEMPHYSCHEM, 2004, 5 (05) : 716 - 720
  • [4] Enhanced Photoanodic Output at an Organic p/n Bilayer in the Water Phase by Means of the Formation of Whiskered Phthalocyanine
    Abe, Toshiyuki
    Tanno, Yoshinori
    Ebina, Toshihiro
    Miyakushi, Shouichi
    Nagai, Keiji
    [J]. ACS APPLIED MATERIALS & INTERFACES, 2013, 5 (04) : 1248 - 1253
  • [5] Organophotocatalysis system of p/n bilayers for wide visible-light-induced molecular hydrogen evolution
    Abe, Toshiyuki
    Chiba, Junpei
    Ishidoya, Misaki
    Nagai, Keiji
    [J]. RSC ADVANCES, 2012, 2 (21): : 7992 - 7996
  • [6] Molecular Hydrogen Evolution by Organic p/n Bilayer Film of Phthalocyanine/Fullerene in the Entire Visible-Light Energy Region
    Abe, Toshiyuki
    Tobinai, Shunsuke
    Taira, Naohiro
    Chiba, Junpei
    Itoh, Takashi
    Nagai, Keiji
    [J]. JOURNAL OF PHYSICAL CHEMISTRY C, 2011, 115 (15) : 7701 - 7705
  • [7] Semiconductor-based Photocatalytic Hydrogen Generation
    Chen, Xiaobo
    Shen, Shaohua
    Guo, Liejin
    Mao, Samuel S.
    [J]. CHEMICAL REVIEWS, 2010, 110 (11) : 6503 - 6570
  • [8] ELECTROCHEMICAL PHOTOLYSIS OF WATER AT A SEMICONDUCTOR ELECTRODE
    FUJISHIMA, A
    HONDA, K
    [J]. NATURE, 1972, 238 (5358) : 37 - +
  • [9] Concurrent synthetic control of dopant (nitrogen) and defect complexes to realize broadband (UV-650 nm) absorption in ZnO nanorods for superior photo-electrochemical performance
    Game, Onkar
    Singh, Upendra
    Gupta, Anubha A.
    Suryawanshi, Anil
    Banpurkar, Arun
    Ogale, Satishchandra
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 2012, 22 (33) : 17302 - 17310
  • [10] Hydrogen and Oxygen Evolution Photocatalysts Synthesized from Strontium Titanate by Controlled Doping and Their Performance in Two-Step Overall Water Splitting under Visible Light
    Hara, Shoichi
    Yoshimizu, Masaharu
    Tanigawa, Satoshi
    Ni, Lei
    Ohtani, Bunsho
    Irie, Hiroshi
    [J]. JOURNAL OF PHYSICAL CHEMISTRY C, 2012, 116 (33) : 17458 - 17463
123