Synthesis and photophysical characterization of novel π-conjugated vinyl sulfides

被引：10

作者：

Bassaco, Mariana M. ^{[1
]}

Moncalves, Matias ^{[1
]}

Rinaldi, Francieli ^{[1
]}

Kaufman, Teodoro S. ^{[2
]}

Silveira, Claudio C. ^{[1
]}

机构：

[1] Univ Fed Santa Maria, UFSM, Dept Quim, BR-97105900 Santa Maria, RS, Brazil

[2] CONICET UNR, IQUIR, Inst Quim Rosario, Rosario, Argentina

来源：

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY | 2014年 / 290卷

关键词：

Vinyl sulfides; Wittig-Horner reaction; Fluorescence; pi-Conjugated system; MOLECULAR SCALE WIRES; ELECTROLUMINESCENT PROPERTIES; 1,3,5,7-TETRASUBSTITUTED ADAMANTANES; 2-PHOTON ABSORPTION; THIOPHENE OLIGOMERS; EMITTING MATERIALS; FACILE SYNTHESIS; QUANTUM YIELDS; DERIVATIVES; FLUORESCENCE;

D O I：

10.1016/j.jphotochem.2014.06.003

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The synthesis and photophysical properties of a series of pi-conjugated vinyl sulfides are described. These compounds exhibited their absorption maxima in the range of 350-366 nm, while the emission spectra displayed peaks in the zone of 421-441 nm; both of them were influenced, although in different degrees, by the extent of the conjugated system. Red-shifted absorption and emission were observed when the pi-conjugation was extended, clearly indicating that the sulfur atom participates as a bridge within these highly conjugated structures. Therefore, this preliminary investigation suggests that vinyl sulfide-based pi-conjugated materials are promising compounds for the development of novel and efficient organic emitters. (C) 2014 Elsevier B.V. All rights reserved.

引用

页码：1 / 10

页数：10

共 50 条

[1] Conjugated vinyl derivatives of chitooligosaccharide: Synthesis and characterization
Cha, SY
Lee, JK
Lim, BS
Lee, TS
Park, WH
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2001, 39 (06) : 880 - 887
[2] Reaction of magnesium alkylidene carbenoids with lithium acetylides and lithium thiolates: a novel synthesis of conjugated enynes and vinyl sulfides
Watanabe, M
Nakamura, M
Satoh, T
TETRAHEDRON, 2005, 61 (18) : 4409 - 4418
[3] Photophysical, crystallographic, and electrochemical characterization of novel conjugated thiopheno azomethines
Bourgeaux, Marie
Perez Guarin, Sergio Andres
Skene, W. G.
JOURNAL OF MATERIALS CHEMISTRY, 2007, 17 (10) : 972 - 979
[4] Synthesis and mass spectral characterization of diisopropylamino-ethanethiol, -sulfides and -disulfides and vinyl sulfides
Rohrbaugh, DK
Berg, FJ
Szafraniec, LJ
Rossman, DI
Durst, HD
Munavalli, S
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 1999, 149 : 95 - 106
[5] Synthesis and photophysical characterization of highly conjugated porphyrin polymers.
Yang, SW
Pristera, A
Murphy, CB
Jones, WE
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2001, 222 : U632 - U632
[6] Methods for the synthesis of vinyl sulfides
Zyk, NV
Beloglazkina, EK
Belova, MA
Dubinina, NS
USPEKHI KHIMII, 2003, 72 (09) : 864 - 883
[7] A CONVENIENT SYNTHESIS OF VINYL SULFIDES
KATRITZKY, AR
AFRIDI, AS
KUZMIERKIEWICZ, W
HELVETICA CHIMICA ACTA, 1991, 74 (08) : 1931 - 1935
[8] A CONVENIENT SYNTHESIS OF VINYL SULFIDES
RODRIGUEZ, AD
NICKON, A
TETRAHEDRON, 1985, 41 (20) : 4443 - 4448
[9] Extending the porphyrin core:: synthesis and photophysical characterization of porphyrins with π-conjugated β-substituents
Ventura, Barbara
Flamigni, Lucia
Marconi, Giancarlo
Lodato, Fabio
Officer, David L.
NEW JOURNAL OF CHEMISTRY, 2008, 32 (01) : 166 - 178
[10] Synthesis and characterization of novel conjugated bisindenocarbazoles
Sonntag, Martin
Strohriegl, Peter
TETRAHEDRON, 2006, 62 (34) : 8103 - 8108

← 1 2 3 4 5 →