A new model on the viscosities of the Zr-Cu-Al liquid alloys

被引：6

作者：

Bo, H. ^{[1
]}

Zhang, Z. H. ^{[1
]}

Hu, J. L. ^{[2
]}

Wang, L. M. ^{[1
]}

机构：

[1] Yanshan Univ, Coll Mat Sci & Engn, State Key Lab Metastable Mat Sci & Technol, Qinhuangdao 066004, Hebei, Peoples R China

[2] Yanshan Univ, Sch Mech Engn, Qinhuangdao 066004, Hebei, Peoples R China

来源：

CALPHAD-COMPUTER COUPLING OF PHASE DIAGRAMS AND THERMOCHEMISTRY | 2020年 / 71卷

基金：

中国国家自然科学基金; 国家重点研发计划;

关键词：

Zr-Cu-Al system; Bulk metallic glasses; Viscosity; Glass-forming ability; CALPHAD; GLASS-FORMING ABILITY; BULK METALLIC-GLASS; MECHANICAL-PROPERTIES; THERMAL-STABILITY; ATOMIC-STRUCTURE; BINARY; TRANSITION; PLASTICITY; SYSTEM; CRYSTALLIZATION;

D O I：

10.1016/j.calphad.2020.102208

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

A new model for the viscosities of multi-component liquid alloys has been proposed within the framework of the CALPHAD (CALculation and PHAse Diagram) method. Unlike the previous CALPHAD-type modeling, the viscosity is described by the Arrhenius equation and the interaction of ternary components could be considered when necessary. With this model, the viscosities of the Zr-Cu-Al liquid alloys were optimized based on the experimental data and the viscosities at liquidus temperatures were calculated over the entire composition range. By analyzing the calculated viscosities of the reported metallic glasses, it is found that alloys with a high glass-forming ability usually possess a viscosity larger than 0.01 Pa.s at liquidus temperature.

引用

页数：6

共 78 条

[1] Agaev A. D., 1980, Izvestiya Akademii Nauk SSSR, Metally, P43
[2] Andrade END, 1934, PHILOS MAG, V17, P698
[3] [Anonymous], 1959, P S HELD NAT PHYS LA
[4] Atomic structure of Zr-Cu-Al and Zr-Ni-Al amorphous alloys
Antonowicz, J.
Louzguine-Luzgin, D. V.
Yavari, A. R.
Georgarakis, K.
Stoica, M.
Vaughan, G.
Matsubara, E.
Inoue, A.
[J]. JOURNAL OF ALLOYS AND COMPOUNDS, 2009, 471 (1-2) : 70 - 73
[5] Arsentev P.P., 1977, TSVETN METALL, V51, P5
[6] Role of Viscosity in Influencing the Glass-Forming Ability of Organic Molecules from the Undercooled Melt State
Baird, Jared A.
Santiago-Quinonez, Darlene
Rinaldi, Carlos
Taylor, Lynne S.
[J]. PHARMACEUTICAL RESEARCH, 2012, 29 (01) : 271 - 284
[7] Barfield R.N., 1955, Journal of the Iron and Steel Institute, V180, P324
[8] Glass formation and mechanical properties of (Cu50Zr50)100-xAlx (x=0, 4, 5, 7) bulk metallic glasses
Baser, T. A.
Das, J.
Eckert, J.
Baricco, M.
[J]. JOURNAL OF ALLOYS AND COMPOUNDS, 2009, 483 (1-2) : 146 - 149
[9] Bendert JC, 2014, INT J THERMOPHYS, V35, P1677, DOI 10.1007/s10765-014-1664-7
[10] Optimization of bulk metallic glass forming compositions in Zr-Cu-Al system by thermodynamic modeling
Bhatt, Jatin
Wu, Jiang
Xia, Junhai
Wang, Qing
Chuang, Dong
Murty, B. S.
[J]. INTERMETALLICS, 2007, 15 (5-6) : 716 - 721

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