Bifunctional organocatalysts for the conversion of CO2, epoxides and aryl amines to 3-aryl-2-oxazolidinones

被引：24
作者：
Xie, Ya-Fei [1 ]
Guo, Cheng [2 ]
Shi, Lei [1 ]
Peng, Bang-Hua [1 ]
Liu, Ning [1 ]
机构：
[1] Shihezi Univ, Key Lab Green Proc Chem Engn Xinjiang Bingtuan, Sch Chem & Chem Engn, North Fourth Rd, Shihezi 832003, Xinjiang, Peoples R China
[2] Zhejiang Univ, Sch Med, Affiliated Hosp 2, Canc Inst, Hangzhou 310009, Zhejiang, Peoples R China
来源：
ORGANIC & BIOMOLECULAR CHEMISTRY | 2019年 / 17卷 / 14期
基金：
中国国家自然科学基金;
关键词：
METAL-ORGANIC FRAMEWORK; CARBON-DIOXIDE; CARBOXYLATIVE CYCLIZATION; CYCLIC CARBONATES; PROPARGYLIC AMINES; EFFICIENT SYNTHESIS; CATALYZED SYNTHESIS; IONIC LIQUIDS; OXAZOLIDINONE SYNTHESIS; COOPERATIVE CATALYSIS;
D O I：
10.1039/c9ob00224c
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A route to synthesize 3-aryl-2-oxazolidinones is developed, which is achieved through a three component reaction between CO2, aryl amines, and epoxides with a binary organocatalytic system composed of organocatalysts and DBU (1,8-diazabicyclo[5.4.0]undec-7-ene). The method allows wide scopes of epoxide and aryl amine substrates with various functional groups under mild reaction conditions. The control experiments indicate that a cyclic carbonate is formed via cycloaddition of epoxides with CO2, which further reacts with the -amino alcohol originating from epoxides and aryl amines, resulting in the formation of 3-aryl-2-oxazolidinones finally.
引用
收藏
页码：3497 / 3506
页数：10
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