New pentafluorothio (SF5)-containing alkyl dibromides

被引：5
作者：
Terjeson, RJ [1 ]
Willenbring, R [1 ]
Gard, GL [1 ]
机构：
[1] PORTLAND STATE UNIV,DEPT CHEM,PORTLAND,OR 97207
来源：
JOURNAL OF FLUORINE CHEMISTRY | 1996年 / 76卷 / 01期
关键词：
pentafluorothio group; alkyl dibromides; preparation; NMR spectroscopy; TR spectroscopy; mass spectrometry;
D O I：
10.1016/0022-1139(95)03341-6
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Preparation of two new SF5-containing compounds and one telomer was achieved by reaction of the olefins CH2=CHBr and CF2=CFBr with SF5Br to form SF5CH2CHBr2 and SF5CF2CFBr2. In the reaction of SF5Br with CF2=CFBr, a waxy solid formed with an average formula of SF5(CF2CFBr)(10)Br.
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页码：63 / 65
页数：3
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