Preparation of phenol from benzene by one-step reaction

被引：29
|
作者：
Liptákov, B [1 ]
Báhidsky, M [1 ]
Hronec, M [1 ]
机构：
[1] Slovak Univ Technol Bratislava, Dept Petr Technol & Petrochem, Bratislava 81237, Slovakia
来源：
APPLIED CATALYSIS A-GENERAL | 2004年 / 263卷 / 01期
关键词：
benzene; oxidation; phenol; hydroxyapatite;
D O I：
10.1016/j.apcata.2003.12.002
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The direct gas-phase oxidation of benzene to phenol with a mixture of oxygen-ammonia-water vapors was studied over mixed calcium-copper-hydroxyapatite catalysts. The effect of various reaction parameters on the transformation of benzene to phenol was tested. About 3% conversion of benzene and 97% phenol selectivity was achieved at atmospheric pressure and the temperature of 450 degreesC in the first 3 h of reaction, when deactivation of the catalyst was not so significant. However, after this period the deactivation of the catalyst was pronounced and probably caused by destruction of an active hydroxyapatite structure of the catalyst. (C) 2003 Elsevier B.V. All rights reserved.
引用
收藏
页码：33 / 38
页数：6
相关论文
共 50 条
  • [31] One-step oxidation of benzene to phenol with H3PW12O40 under photoirradiation: Effect of operating conditions
    Wang, Ziru
    Hojo, Hajime
    Einaga, Hisahiro
    CHEMICAL ENGINEERING JOURNAL, 2022, 427
  • [32] One-step photocatalytic benzene hydroxylation over iron (II) phthalocyanine: A new application for an old catalyst
    Asghari, Saeid
    Farahmand, Shohreh
    Razavizadeh, Jalal. S.
    Ghiaci, Mehran
    JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2020, 392
  • [33] ONE-STEP HYDROXYLATION OF BENZENE TO PHENOL .2. GAS-PHASE N2O OXIDATION OVER MO/FE/BOROSILICATE MOLECULAR-SIEVE
    YOO, JS
    SOHAIL, AR
    GRIMMER, SS
    CHOIFENG, C
    CATALYSIS LETTERS, 1994, 29 (3-4) : 299 - 310
  • [34] One-step semi-continuous cyclohexanone production via hydrogenation of phenol in a submerged ceramic membrane reactor
    Jiang, Hong
    Qu, Zhengyan
    Li, Ying
    Huang, Jun
    Chen, Rizhi
    Xing, Weihong
    CHEMICAL ENGINEERING JOURNAL, 2016, 284 : 724 - 732
  • [35] One-step phenol production from a water–toluene mixture using radio frequency in-liquid plasma
    Muhammad AGUNG
    Shinfuku NOMURA
    Shinobu MUKASA
    Hiromichi TOYOTA
    Otsuka KAZUHIKO
    Hidekazu GOTO
    Plasma Science and Technology, 2017, (05) : 64 - 71
  • [36] One-Step Benzene Hydroxylation with Copper Oxide Supported on Activated Red Mud Catalyst
    Singh, Shivani
    Rawat, Manish
    Lama, Prem
    Khatun, Rubina
    Kaishyop, Jyotishman
    Kothari, Anil Chandra
    Pal, Rohan Singh
    Rana, Swati
    Khan, Tuhin Surva
    Bal, Rajaram
    ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2024, 12 (35): : 13176 - 13184
  • [37] Alternating-Current Electrolysis for the Production of Phenol from Benzene
    Lee, Byungik
    Naito, Hiroto
    Nagao, Masahiro
    Hibino, Takashi
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, 51 (28) : 6961 - 6965
  • [38] Direct synthesis of phenol from benzene over hydroxyapatite catalysts
    Liptáková, B
    Hronec, M
    Cvengrosová, Z
    CATALYSIS TODAY, 2000, 61 (1-4) : 143 - 148
  • [39] One-Step Synthesis of Aniline From Benzene With Hydroxylamine Over V-MCM-41 Mesoporous Molecular Sieves
    Yang, Chunhua
    Chen, Gang
    JOURNAL OF THE CHEMICAL SOCIETY OF PAKISTAN, 2016, 38 (02): : 282 - 286
  • [40] The AlphOxTM process or the one‐step hydroxylation of benzene into phenol by nitrous oxide. Understanding and tuning the ZSM‐5 catalyst activities
    Patrick P. Notté
    Topics in Catalysis, 2000, 13 : 387 - 394
12345