New rhodamine dimer probes for mercury detection via color changes and enhancement of the fluorescence emission: Fast recognition in cellulose supported devices

被引:38
作者
Nunez, Cristina [1 ,2 ]
Diniz, Mario [1 ]
Dos Santos, Alcindo A. [3 ]
Capelo, Jose Luis [1 ]
Lodeiro, Carlos [1 ]
机构
[1] NOVA Univ Lisbon, Fac Sci & Technol, Dept Chem, REQUIMTE,CQFB,BIOSCOPE Grp, P-2829516 Caparica, Portugal
[2] Canterbury Christ Church Univ, Dept Geog & Life Sci, Ecol Res Grp, Canterbury CT1 1QU, Kent, England
[3] Univ Sao Paulo, Inst Quim, BR-05508000 Sao Paulo, Brazil
基金
巴西圣保罗研究基金会;
关键词
Rhodamine; Mercury ion; Fluorescence; Sensor; Solid support; Aqueous detection; SELECTIVE FLUORESCENT; HG2+ IONS; RAPID DETECTION; ENERGY-TRANSFER; CHEMOSENSOR; SENSOR; CHEMODOSIMETER; CELLS;
D O I
10.1016/j.dyepig.2013.09.019
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Two rhodamine dimer compounds exhibiting high selectivity and sensitivity for Hg2+ over other metal cations have been studied in absolute ethanol solution. Increase in the absorption and emission signals with a color change from colorless to pink were observed in both cases. Recognition of Hg2+ with both compounds in the gas phase was also explored. Immobilization of the rhodamine probes in cellulose supported systems to evaluate their efficiency on the fast detection of Hg2+ in aqueous phase was also reported. (C) 2013 Elsevier Ltd. All rights reserved.
引用
收藏
页码:156 / 163
页数:8
相关论文
共 49 条
[1]   Synthesis and applications of Rhodamine derivatives as fluorescent probes [J].
Beija, Mariana ;
Afonso, Carlos A. M. ;
Martinho, Jose M. G. .
CHEMICAL SOCIETY REVIEWS, 2009, 38 (08) :2410-2433
[2]  
Berlman I. B., 1971, HDB FLUORESCENCE SPE
[3]   New Fluorogenic Sensors for Hg2+ Ions: Through-Bond Energy Transfer from Pentaquinone to Rhodamine [J].
Bhalla, Vandana ;
Roopa ;
Kumar, Manoj ;
Sharma, Parduman Raj ;
Kaur, Tandeep .
INORGANIC CHEMISTRY, 2012, 51 (04) :2150-2156
[4]   Ecological effects, transport, and fate of mercury: a general review [J].
Boening, DW .
CHEMOSPHERE, 2000, 40 (12) :1335-1351
[5]   Abiotic methylation of mercury in the aquatic environment [J].
Celo, Valbona ;
Lean, David R. S. ;
Scott, Susannah L. .
SCIENCE OF THE TOTAL ENVIRONMENT, 2006, 368 (01) :126-137
[6]   Hg2+ Selective Fluorescent and Colorimetric Sensor: Its Crystal Structure and Application to Bioimaging [J].
Chen, Xiaoqiang ;
Nam, Seong-Won ;
Jou, Min Jung ;
Kim, Youngmee ;
Kim, Sung-Jin ;
Park, Sungsu ;
Yoon, Juyoung .
ORGANIC LETTERS, 2008, 10 (22) :5235-5238
[7]   A New Fluorescent Chemodosimeter for Hg2+ : Selectivity, Sensitivity, and Resistance to Cys and GSH [J].
Du, Jianjun ;
Fan, Jiangli ;
Peng, Xiaojun ;
Sun, Pingping ;
Wang, Jingyun ;
Li, Honglin ;
Sun, Shiguo .
ORGANIC LETTERS, 2010, 12 (03) :476-479
[8]   Marine biogeochemical cycling of mercury [J].
Fitzgerald, William F. ;
Lamborg, Carl H. ;
Hammerschmidt, Chad R. .
CHEMICAL REVIEWS, 2007, 107 (02) :641-662
[9]   Investigation of equilibria in solution. Determination of equilibrium constants with the HYPERQUAD suite of programs [J].
Gans, P ;
Sabatini, A ;
Vacca, A .
TALANTA, 1996, 43 (10) :1739-1753
[10]   Cognitive performance of children prenatally exposed to "safe" levels of methylmercury [J].
Grandjean, P ;
Weihe, P ;
White, RF ;
Debes, F .
ENVIRONMENTAL RESEARCH, 1998, 77 (02) :165-172