Highly luminescent and transparent ZnO quantum dots-epoxy composite used for white light emitting diodes

被引:31
作者
Huang, Jia Jia [1 ]
Ye, Yi Bin [1 ]
Lei, Zhou Qiao [1 ]
Ye, Xiao Ji [1 ]
Rong, Min Zhi [1 ]
Zhang, Ming Qiu [1 ]
机构
[1] Sun Yat Sen Univ, Sch Chem & Chem Engn, Key Lab Polymer Composite & Funct Mat, Minist Educ, Guangzhou 510275, Guangdong, Peoples R China
关键词
VISIBLE PHOTOLUMINESCENCE; ENCAPSULATING MATERIALS; NANOPARTICLES; NANOCOMPOSITES; PHOSPHORS; EMISSION;
D O I
10.1039/c3cp55098b
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
By using epoxy silane as a modifier and stabilizer, ZnO quantum dots (QDs) were synthesized by a one-step precipitation approach. The ZnO QDs acquired showed satisfactory redispersibility and exhibited strong and stable photoluminescence in both solution and dry states. When the ZnO QDs content was as high as 8 wt%, the ZnO QDs-epoxy nanocomposite was still highly transparent and luminescent. Accordingly, the ZnO QDs can be used as a luminescent material, and a cool white light emitting diode (WLED) lamp was made by encapsulating a UV chip with the nanocomposite, without traditional tricolor rare earth phosphors. Additionally, the high loading nanocomposite possessed high ultraviolet resistance, which would help to improve the lifetime of the WLED.
引用
收藏
页码:5480 / 5484
页数:5
相关论文
共 29 条
  • [1] Enhanced visible photoluminescence in ZnO quantum dots by promotion of oxygen vacancy formation
    Asok, Adersh
    Gandhi, Mayuri N.
    Kulkarni, A. R.
    [J]. NANOSCALE, 2012, 4 (16) : 4943 - 4946
  • [2] Light Converting Inorganic Phosphors for White Light-Emitting Diodes
    Chen, Lei
    Lin, Chun-Che
    Yeh, Chiao-Wen
    Liu, Ru-Shi
    [J]. MATERIALS, 2010, 3 (03): : 2172 - 2195
  • [3] ZnO-based ultra-violet light emitting diodes and nanostructures fabricated by atomic layer deposition
    Chen, Miin-Jang
    Yang, Jer-Ren
    Shiojiri, Makoto
    [J]. SEMICONDUCTOR SCIENCE AND TECHNOLOGY, 2012, 27 (07)
  • [4] Quantum dot integrated LEDs using photonic and excitonic color conversion
    Demir, Hilmi Volkan
    Nizamoglu, Sedat
    Erdem, Talha
    Mutlugun, Evren
    Gaponik, Nikolai
    Eychmueller, Alexander
    [J]. NANO TODAY, 2011, 6 (06) : 632 - 647
  • [5] Stable aqueous dispersion of ZnO quantum dots with strong blue emission via simple solution route
    Fu, Ying-Song
    Du, Xi-Wen
    Kulinich, Sergei A.
    Qiu, Jian-Sheng
    Qin, Wen-Jing
    Li, Rui
    Sun, Jing
    Liu, Jim
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (51) : 16029 - 16033
  • [6] Bulk synthesis of transparent and homogeneous polymeric hybrid materials with ZnO quantum dots and PMMA
    Li, Shanghua
    Toprak, Muhammet S.
    Jo, Yun Suk
    Dobson, Jon
    Kim, Do Kyung
    Muhammed, Mamoun
    [J]. ADVANCED MATERIALS, 2007, 19 (24) : 4347 - +
  • [7] Transparent and Light-Emitting Epoxy Super-Nanocomposites Containing ZnO-QDs/SiO2 Nanocomposite Particles as Encapsulating Materials for Solid-State Lighting
    Li, Yuan-Qing
    Yang, Yang
    Fu, Shao-Yun
    Yi, Xiao-Yan
    Wang, Liang-Chen
    Chen, Hong-Da
    [J]. JOURNAL OF PHYSICAL CHEMISTRY C, 2008, 112 (47) : 18616 - 18622
  • [8] Light-emitting diodes fabricated from small-size ZnO quantum dots
    Qiao, Q.
    Li, B. H.
    Shan, C. X.
    Liu, J. S.
    Yu, J.
    Xie, X. H.
    Zhang, Z. Z.
    Ji, T. B.
    Jia, Y.
    Shen, D. Z.
    [J]. MATERIALS LETTERS, 2012, 74 : 104 - 106
  • [9] Solid-state light sources getting smart
    Schubert, EF
    Kim, JK
    [J]. SCIENCE, 2005, 308 (5726) : 1274 - 1278
  • [10] Synthesis and Luminescent Properties of Li3Ba2Y3(MoO4)8:Ln3+ (Ln = Eu, Tb, Dy) Phosphors for UV-LEDs
    Shang, Mengmeng
    Li, Guogang
    Kang, Xiaojiao
    Yang, Dongmei
    Lin, Jun
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2011, 158 (05) : H565 - H571