Carbyne Polysulfide as a Novel Cathode Material for Rechargeable Magnesium Batteries

被引：11
|
作者：
NuLi, Yanna [1 ,2 ]
Chen, Qiang [1 ,2 ]
Wang, Weikun [3 ]
Wang, Ying [4 ]
Yang, Jun [1 ,2 ]
Wang, Jiulin [1 ,2 ]
机构：
[1] Shanghai Jiao Tong Univ, Dept Chem Engn, Shanghai 200240, Peoples R China
[2] Shanghai Jiao Tong Univ, Hirano Inst Mat Innovat, Shanghai 200240, Peoples R China
[3] Res Inst Chem Def, Beijing 100083, Peoples R China
[4] Shanghai Jiao Tong Univ, Minist Educ, Key Lab forThin Film & Microfabricat, Shanghai 200240, Peoples R China
来源：
SCIENTIFIC WORLD JOURNAL | 2014年
关键词：
ELECTROLYTE-SOLUTIONS; INSERTION;
D O I：
10.1155/2014/107918
中图分类号：
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号：
07 ; 0710 ; 09 ;
摘要：
We report the formation of carbyne polysulfide by coheating carbon containing carbyne moieties and elemental sulfur. The product is proved to have a sp(2) hybrid carbon skeleton with polysulfide attached on it. The electrochemical performance of carbyne polysulfide as a novel cathode material for rechargeable magnesium batteries is firstly investigated. The material exhibits a high discharge capacity of 327.7 mAh g(-1) at 3.9 mA g(-1). These studies show that carbyne polysulfide is a promising candidate as cathode material for rechargeable Mg batteries if the capacity retention can be significantly improved.
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页数：7
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