Incorporating CdTe nanocrystals into polystyrene microspheres: Towards robust fluorescent beads

被引:107
作者
Yang, Yunhua
Wen, Zhongkai
Dong, Yuping
Gao, Mingyuan
机构
[1] Chinese Acad Sci, Inst Chem, Key Lab Colloid Interface Sci & Chem Thermodynam, Beijing 100080, Peoples R China
[2] Beijing Inst Technol, Coll Mat Sci & Engn, Beijing 100081, Peoples R China
关键词
CdTe; fluorescence; nanocrystals; photostability; polystyrene;
D O I
10.1002/smll.200600086
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The method for incorporation of the CdTe nanocrystals into polystyrene microspheres was described. The use of polystyrene for effectively enhancing the photostability of the Q-dots within the PS beads, was also analyzed. The photoluminescence (PL)investigations revealed that the PL efficiency of the CdTe dots was reduced by a factor of 1.7-2.0. It was observed that the fluorescence-quenching effects were mainly caused by free radicals and were strongly dependent on the presence of oxygen as well as the nature of the free radicals. The photobleaching experiments were performed by continuously illuminating the composite beads using ultraviolet light at 392nm. The results demonstrated that the composite beads simultaneously incorporating the two types of dots show an emission profile mainly determined by their input ratio.
引用
收藏
页码:898 / 901
页数:4
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