FT-ICR MS characterization of bio-binders for road pavement from HTL of microalgae residues

被引:12
作者
Geantet, Christophe [1 ]
Laurenti, Dorothee [1 ]
Guilhaume, Nolven [1 ]
Lorentz, Chantal [1 ]
Borghol, Ilef [2 ,3 ]
Bujoli, Bruno [2 ]
Chailleux, Emmanuel [3 ]
Checa, Ruben [1 ]
Schramm, Sebastien [4 ,5 ]
Carre, Vincent [4 ,5 ]
Aubriet, Frederic [4 ,5 ]
Queffelec, Clemence [3 ]
机构
[1] Univ Claude Bernard Lyon 1, Univ Lyon, CNRS, UMR 5256,IRCELYON, F-69626 Villeurbanne, France
[2] Nantes Univ, CNRS, UMR 6230, CEISAM, F-44000 Nantes, France
[3] Univ Gustave Eiffel, Campus Nantes,Allee Ponts & Chaussees,CS 5004, F-44344 Bouguenais, France
[4] Univ Lorraine, LCP 2MC, F-57000 Metz, France
[5] Univ Lorraine, Reseau Natl Spectrometrie Masse FT ICR Tres Haul, F-57000 Metz, France
来源
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING | 2022年 / 10卷 / 03期
关键词
Hydrothermal liquefaction; Microalgae; Scenedesmus residues; FT-ICR MS; Biobinder; Rheology; Ceria; RESONANCE MASS-SPECTROMETRY; HYDROTHERMAL LIQUEFACTION; ELECTROSPRAY-IONIZATION; SUBCRITICAL WATER; CARBOXYLIC-ACIDS; OIL; BIOMASS; CRUDE; HYDROTREATMENT; KETONIZATION;
D O I
10.1016/j.jece.2022.107361
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
ABS T R A C T Hydrothermal liquefaction (HTL) of microalgae-derived feedstocks into a bio-binder was investigated in the absence or presence of a catalyst. The resulting products of HTL of Scenedesmus species (sp.) residues present rheological properties close to those of a petroleum-derived bitumen. The chemical composition of the biobinder was analysed by two-dimensional gas chromatography (GCxGC-MS), gel permeation chromatography (GPC), and negative and positive-ion laser desorption/ionization FT-ICR MS to provide a complementa r y analysis of the biobinder and understanding of the role of catalysts. A detailed description of the heav y nitrogen compounds contained in the biobitumen is given.
引用
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页数:11
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