Grafting of Poly(acrylic acid) onto an Aluminum Surface

被引：15
作者：
Barroso-Bujans, Fabienne [1 ]
Serna, Rosalia [2 ]
Sow, Eva [1 ]
Fierro, Jose L. G. [3 ]
Veith, Michael [1 ,4 ]
机构：
[1] Univ Saarland, Inst Inorgan Chem, D-66041 Saarbrucken, Germany
[2] CSIC, Inst Opt, Laser Proc Grp, E-28006 Madrid, Spain
[3] CSIC, Inst Catalisis & Petr Quim, Madrid 28049, Spain
[4] INM, D-66123 Saarbrucken, Germany
来源：
LANGMUIR | 2009年 / 25卷 / 16期
关键词：
CARBON NANOTUBES; POLYMERIZATION; IMPLANTS; FILMS;
D O I：
10.1021/la900518s
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Grafting of poly(acrylic acid) (PAA) onto all aluminum surface was successfully achieved by free radical polymerization of acrylic acid using typical radical initiators, benzoyl peroxide and 2,2'-azobisisobutyronitrile. Both spotlike and brush morphologies were achieved. A complete coverage of PAA oil in aluminum surface was then achieved by using a thermal chemical vapor deposition process. The PAA thickness was determined by ellipsometry and the superficial chemical composition by X-ray photoelectron spectroscopy (XPS). Grazing angle Fourier transform infrared (FTIR) spectroscopy confirmed the presence of carboxylic acid groups on the surface, and the contact angle Measurements revealed a decreasing free surface energy of aluminum due to the polymer surface covering.
引用
收藏
页码：9094 / 9100
页数：7
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