A Facile Template Approach to High-Nuclearity Silver(I) Alkynyl Clusters

被引：141
作者：
Bian, Shu-Dan [1 ]
Wu, Hua-Bin [1 ]
Wang, Quan-Ming [1 ]
机构：
[1] Xiamen Univ, Dept Chem, Coll Chem & Chem Engn, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Peoples R China
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 29期
关键词：
alkyne ligands; cage compounds; cluster compounds; silver; template synthesis; ANION RECOGNITION; COORDINATION; HIGHLIGHTS; CHEMISTRY;
D O I：
10.1002/anie.200902279
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Peanut clusters: Anion templates are used in a facile approach for the synthesis of highnuclearity silver clusters. The cluster nuclearity can be controlled by adjusting the size of the templating anions and by using different alkynyl ligands. The largest silver alkynyl cluster, which consists of 35 silver(I) centers in the shape of a peanut, has been prepared by using chromate anions as templates (see picture). © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.
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收藏
页码：5363 / 5365
页数：3
相关论文
共 19 条
[1]   EXPANDING ROLES FOR TEMPLATES IN SYNTHESIS [J].
ANDERSON, S ;
ANDERSON, HL ;
SANDERS, JKM .
ACCOUNTS OF CHEMICAL RESEARCH, 1993, 26 (09) :469-475
[2]  
Anson C.E., 2008, ANGEW CHEM, V120, P1346
[3]   Synthesis and crystal structures of the ligand-stabilized over chalcogenide clusters [Ag154Se77(dppxy)18], [Ag320(StBu)60S130(dppp)12], [Ag352S128(StC5H11)96], and [Ag490S188(StC5H11)114] [J].
Anson, Christopher E. ;
Eichhofer, Andreas ;
Issac, Ibrahim ;
Fenske, Dieter ;
Fuhr, Olaf ;
Sevillano, Paloma ;
Persau, Claudia ;
Stalke, Dietmar ;
Zhang, Jiatao .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (07) :1326-1331
[4]  
Beer P.D., 2001, ANGEW CHEM, V113, P502
[5]  
Beer PD, 2001, ANGEW CHEM INT EDIT, V40, P486, DOI 10.1002/1521-3773(20010202)40:3<486::AID-ANIE486>3.0.CO
[6]  
2-P
[7]   High-Nuclearity Silver Clusters Templated by Carbonates Generated from Atmospheric Carbon Dioxide Fixation [J].
Bian, Shu-Dan ;
Jia, Jian-Hua ;
Wang, Quan-Ming .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (10) :3422-+
[8]   Anion receptor chemistry: highlights from 1999 [J].
Gale, PA .
COORDINATION CHEMISTRY REVIEWS, 2001, 213 :79-128
[9]   Anion coordination and anion-directed assembly: highlights from 1997 and 1998 [J].
Gale, PA .
COORDINATION CHEMISTRY REVIEWS, 2000, 199 :181-233
[10]   A keplerate magnetic cluster featuring an icosidodecahedron of Ni(II) ions encapsulating a dodecahedron of La(III) ions [J].
Kong, Xiang-Jian ;
Ren, Yan-Ping ;
Long, La-Sheng ;
Zheng, Zhiping ;
Huang, Rong-Bin ;
Zheng, Lan-Sun .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (22) :7016-+
12