Imaging of diamond defect sites by electron-beam-induced current

The method of electron-beam-induced current (EBIC) was used to visualize the defect sites on a p-type (boron-doped) diamond (001) film. For this purpose, an Ag-Schottky layer (similar to 2 mm x similar to 2 mm x similar to 50 nm) was deposited on the oxygen-terminated p-type diamond (001) film and used as a source of EBIC signal. The signal current of EBIC image appeared to be as large as similar to 1200 times that of the incident electron-beam current and the difference range in image intensity was also large (1-1200). The observed EBIC images showed many kinds of signatures that are possible 'killer' defects for Schottky devices. In order to identify 'killer' defects in the EBIC image, an array of Ag-dots (similar to 40 x similar to 50 mu m(2)) was deposited on an oxygen-terminated p-type diamond (001) film and I-V characteristics were measured on 53 Ag-dots. The resulting I-V characteristics showed that 21 Ag-dots reside on 'killer' defects. Comparison between the EBIC image and the positions of Ag-dots residing on 'killer' defects showed that large dark dots in EBIC image correspond to the position of 'killer' defects. The number density of the large dark dots (i.e., 'killer' defects) was similar to 10(4)/cm(2) in the present sample. It is suggested that a high yield Schottky-junction device may be fabricated by avoiding these 'killer' defects by the use of EBIC. (C) 2015 Elsevier B.V. All rights reserved.