An unexpected discovery in the Willgerodt-Kindler reaction of acetophenone - the formation of the 4-(benzoylthiocarbonyl)morpholine

被引：12
|
作者：
Liu, Wei-wei [1 ]
Zhao, Yue-Qiang
Xu, Rui-Bo
Tang, Li-Juan
Hu, Hong-Wen
机构：
[1] Huaihai Inst Technol, Dept Chem Engn, Lianyungang 222005, Jiangsu, Peoples R China
[2] Nanjing Univ, Dept Chem, Nanjing 210093, Jiangsu, Peoples R China
来源：
CHINESE JOURNAL OF CHEMISTRY | 2006年 / 24卷 / 10期
关键词：
4-(benzylthiocarbonyl)morpholine; 4-(benzoylthiocarbonyl)morpholine; acetophenone; Willgerodt-Kindler reaction; crystal structure;
D O I：
10.1002/cjoc.200690278
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The Wiligerodt-Kindler reaction of acetophenone was studied. Apart from the normal product 4-(benzylthiocarbonyl)morpholine, another product 4-(benzoylthiocarbonyl)morpholine was obtained unexpectedly. The structure of the latter was confirmed by IR, (1)H NMR spectra and X-ray diffraction analysis. The mechanism of the reaction was discussed.
引用
收藏
页码：1472 / 1475
页数：4
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