An unexpected discovery in the Willgerodt-Kindler reaction of acetophenone - the formation of the 4-(benzoylthiocarbonyl)morpholine

被引：12

作者：

Liu, Wei-wei ^{[1
]}

Zhao, Yue-Qiang

Xu, Rui-Bo

Tang, Li-Juan

Hu, Hong-Wen

机构：

[1] Huaihai Inst Technol, Dept Chem Engn, Lianyungang 222005, Jiangsu, Peoples R China

[2] Nanjing Univ, Dept Chem, Nanjing 210093, Jiangsu, Peoples R China

来源：

CHINESE JOURNAL OF CHEMISTRY | 2006年 / 24卷 / 10期

关键词：

4-(benzylthiocarbonyl)morpholine; 4-(benzoylthiocarbonyl)morpholine; acetophenone; Willgerodt-Kindler reaction; crystal structure;

D O I：

10.1002/cjoc.200690278

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The Wiligerodt-Kindler reaction of acetophenone was studied. Apart from the normal product 4-(benzylthiocarbonyl)morpholine, another product 4-(benzoylthiocarbonyl)morpholine was obtained unexpectedly. The structure of the latter was confirmed by IR, (1)H NMR spectra and X-ray diffraction analysis. The mechanism of the reaction was discussed.

引用

页码：1472 / 1475

页数：4

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