In Pursuit of an Ideal Carbon-Carbon Bond-Forming Reaction: Development and Applications of the Hydrovinylation of Olefins

被引：92
|
作者：
RajanBabu, T. V. [1 ]
机构：
[1] Ohio State Univ, Dept Chem, Columbus, OH 43210 USA
来源：
SYNLETT | 2009年 / 06期
基金：
美国国家科学基金会; 美国国家卫生研究院;
关键词：
carbon-carbon bond formation; hydrovinylations; asymmetric catalysis; ligand effects; transition metals; NICKEL-CATALYZED HYDROVINYLATION; CHAIN STEREOCHEMISTRY PROBLEM; STEROID SIDE-CHAINS; WHIP PSEUDOPTEROGORGIA-ELISABETHAE; C-C LINKAGES; ASYMMETRIC HYDROVINYLATION; PHOSPHORAMIDITE LIGANDS; HIGHLY EFFICIENT; ENANTIOSELECTIVE HYDROVINYLATION; STYRENE DERIVATIVES;
D O I：
10.1055/s-0028-1088213
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Attempts to introduce the highly versatile vinyl group into other organic molecules in a chemo-, regio-, and stereoselective fashion via catalytic activation of ethylene provided challenging opportunities to explore new ligand and salt effects in homogeneous catalysis. This review provides a personal account of the development of enantioselective reactions involving ethylene.
引用
收藏
页码：853 / 885
页数：33
相关论文
共 33 条
  • [31] Room Temperature, Reductive Alkylation of Activated Methylene Compounds: Carbon-Carbon Bond Formation Driven by the Rhodium-Catalyzed Water-Gas Shift Reaction
    Denmark, Scott E.
    Ibrahim, Malek Y. S.
    Ambrosi, Andrea
    ACS CATALYSIS, 2017, 7 (01): : 613 - 630
  • [32] Cluster-mediated alkenyl isomerism and carbon-carbon bond formation: The reaction of the unsaturated benzothiazole cluster [Os3(CO)9(μ3-C7H4NS)(μ-H)] with dimethyl acetylenedicarboxylate
    Uddin, Kh. Mahid
    Ghosh, Shishir
    Raha, Arun K.
    Hogarth, Graeme
    Rosenberg, Edward
    Sharmin, Ayesha
    Hardcastle, Kenneth I.
    Kabir, Shariff E.
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2010, 695 (10-11) : 1435 - 1440
  • [33] Carbon-carbon and carbon-chlorine bond formation on reaction of iodine(III) reagents with the bis(alkynyl)palladium(II) motif, and structural chemistry of trans-Pd(CC-o-Tol)2(PMe2Ph)2] and trans-[PdCl(CC-o-Tol)(PMe2Ph)2]
    Sharma, Manab
    Canty, Allan J.
    Gardiner, Michael G.
    Jones, Roderick C.
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2011, 696 (07) : 1441 - 1444
1234