In Pursuit of an Ideal Carbon-Carbon Bond-Forming Reaction: Development and Applications of the Hydrovinylation of Olefins

被引：93

作者：

RajanBabu, T. V. ^{[1
]}

机构：

[1] Ohio State Univ, Dept Chem, Columbus, OH 43210 USA

来源：

SYNLETT | 2009年 / 06期

基金：

美国国家卫生研究院; 美国国家科学基金会;

关键词：

carbon-carbon bond formation; hydrovinylations; asymmetric catalysis; ligand effects; transition metals; NICKEL-CATALYZED HYDROVINYLATION; CHAIN STEREOCHEMISTRY PROBLEM; STEROID SIDE-CHAINS; WHIP PSEUDOPTEROGORGIA-ELISABETHAE; C-C LINKAGES; ASYMMETRIC HYDROVINYLATION; PHOSPHORAMIDITE LIGANDS; HIGHLY EFFICIENT; ENANTIOSELECTIVE HYDROVINYLATION; STYRENE DERIVATIVES;

D O I：

10.1055/s-0028-1088213

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Attempts to introduce the highly versatile vinyl group into other organic molecules in a chemo-, regio-, and stereoselective fashion via catalytic activation of ethylene provided challenging opportunities to explore new ligand and salt effects in homogeneous catalysis. This review provides a personal account of the development of enantioselective reactions involving ethylene.

引用

页码：853 / 885

页数：33

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[2]

2-#

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