General expressions for the coupling coefficient, quality and filling factors for a cavity with an insert using energy coupled mode theory

被引:13
作者
Elnaggar, Sameh Y. [1 ]
Tervo, Richard [1 ]
Mattar, Saba M. [2 ,3 ]
机构
[1] Univ New Brunswick, Dept Elect & Comp Engn, Fredericton, NB E3B 6E2, Canada
[2] Univ New Brunswick, Dept Chem, Fredericton, NB E3B 6E2, Canada
[3] Univ New Brunswick, Ctr Laser Atom & Mol Sci, Fredericton, NB E3B 6E2, Canada
基金
加拿大自然科学与工程研究理事会;
关键词
Electron paramagnetic resonance; Dielectric resonators; Resonance cavity; Resonator modes; Coupled mode theory; Coupled modes; Coupling coefficient; Quality factor; Filling factor; Resonator frequency; Finite element methods; Magnetic field distributions; Electric field distributions; Spectrometer sensitivity; Signal-to-noise ratio; ELECTRON-PARAMAGNETIC-RESONANCE; STACKED DIELECTRIC RESONATOR; LOOP-GAP RESONATOR; SPIN-RESONANCE; EPR; SENSITIVITY; TRANSPARENT;
D O I
10.1016/j.jmr.2014.01.018
中图分类号
Q5 [生物化学];
学科分类号
071010 ; 081704 ;
摘要
A cavity (CV) with a dielectric resonator (DR) insert forms an excellent probe for the use in electron paramagnetic resonance (EPR) spectrometers. The probe's coupling coefficient, K, the quality factor, Q and the filling factor, n are vital in assessing the EPR spectrometer's performance. Coupled mode theory (CMT) is used to derive general expressions for these parameters. For large permittivity the dominating factor in it is the ratio of the DR and CV cross sectional areas rather than the dielectric constant. Thus in some cases, resonators with low dielectric constant can couple much stronger with the cavity than do resonators with a high dielectric constant. When the DR and CV frequencies are degenerate, the coupled n is the average of the two uncoupled ones. In practical EPR probes the coupled 17 is approximately half of that of the DR. The Q of the coupled system generally depends on the eigenvectors, uncoupled frequencies (omega(1), omega(2)) and the individual quality factors (Q(1), Q(2)). It is calculated for different probe configurations and found to agree with the corresponding HFSS (R) simulations. Provided there is a large difference between the Q(1) Q2 pair and the frequencies of DR and CV are degenerate, Q is approximately equal to double the minimum of Q(1) and Q(2). In general, the signal enhancement ratio, I-with (insert)/I-empty, is obtained from Q and n. For low loss DRs it only depends on n(1)/n(2). However, when the DR has a low Q, the uncoupled Qs are also needed. In EPR spectroscopy it is desirable to excite only a single mode. The separation between the modes, phi, is calculated as a function of k and Q. It is found to be significantly greater than five times the average bandwidth. Thus for practical probes, it is possible to excite one of the coupled modes without exciting the other. The CMT expressions derived in this article are quite general and are in excellent agreement with the lumped circuit approach and finite numerical simulations. Hence they can also be applied to a loop-gap resonator in a cavity. For the design effective EPR probes, one needs to consider the it, Q and n parameters. (C) 2014 Elsevier Inc. All rights reserved.
引用
收藏
页码:57 / 66
页数:10
相关论文
共 41 条
[1]   ELECTRON-SPIN-RESONANCE AND ENDOR APPLICATIONS OF LOOP GAP RESONATORS WITH DISTRIBUTED CIRCUIT COUPLING [J].
ANDERSON, JR ;
VENTERS, RA ;
BOWMAN, MK ;
TRUE, AE ;
HOFFMAN, BM .
JOURNAL OF MAGNETIC RESONANCE, 1985, 65 (01) :165-168
[2]   Distance measurements in the borderline region of applicability of CW EPR and DEER: A model study on a homologous series of spin-labelled peptides [J].
Banham, J. E. ;
Baker, C. M. ;
Ceola, S. ;
Day, I. J. ;
Grant, G. H. ;
Groenen, E. J. J. ;
Rodgers, C. T. ;
Jeschke, G. ;
Timmel, C. R. .
JOURNAL OF MAGNETIC RESONANCE, 2008, 191 (02) :202-218
[3]   New developments in high field electron paramagnetic resonance with applications in structural biology [J].
Bennati, M ;
Prisner, TF .
REPORTS ON PROGRESS IN PHYSICS, 2005, 68 (02) :411-448
[4]   Transparent miniature dielectric resonator for electron paramagnetic resonance experiments [J].
Blank, A ;
Stavitski, E ;
Levanon, H ;
Gubaydullin, F .
REVIEW OF SCIENTIFIC INSTRUMENTS, 2003, 74 (05) :2853-2859
[5]   Measurement of large distances in biomolecules using double-quantum filtered refocused electron spin-echoes [J].
Borbat, PP ;
Davis, JH ;
Butcher, SE ;
Freed, JH .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (25) :7746-7747
[6]   The determination of pair distance distributions by pulsed ESR using Tikhonov regularization [J].
Chiang, YW ;
Borbat, PP ;
Freed, JH .
JOURNAL OF MAGNETIC RESONANCE, 2005, 172 (02) :279-295
[7]   MICROWAVE BANDPASS FILTERS CONTAINING HIGH-Q DIELECTRIC RESONATORS [J].
COHN, SB .
IEEE TRANSACTIONS ON MICROWAVE THEORY AND TECHNIQUES, 1968, MT16 (04) :218-&
[8]   Resonant microwave cavity for 8.5-12 GHz optically detected electron spin resonance with simultaneous nuclear magnetic resonance [J].
Colton, J. S. ;
Wienkes, L. R. .
REVIEW OF SCIENTIFIC INSTRUMENTS, 2009, 80 (03)
[9]   A DIELECTRIC SAMPLE RESONATOR DESIGN FOR ENHANCED SENSITIVITY OF ELECTRON-PARAMAGNETIC-RES SPECTROSCOPY [J].
DYKSTRA, RW ;
MARKHAM, GD .
JOURNAL OF MAGNETIC RESONANCE, 1986, 69 (02) :350-355
[10]  
Eaton G.R., COMPR COORD CHEM 2