Study of the linearity of the voltage-current relationship in ion-exchange membranes using the network simulation method

被引：9
作者：
Moya, AA [1 ]
Horno, J [1 ]
机构：
[1] Univ Jaen, Fac Ciencias Expt, Dept Fis, Jaen 23071, Spain
来源：
JOURNAL OF MEMBRANE SCIENCE | 2004年 / 235卷 / 1-2期
关键词：
electrodiffusion processes; Nernst-Planck and Poisson equations; network simulation method; ion-exchange membranes; PSPICE modelling;
D O I：
10.1016/j.memsci.2004.02.002
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
The conditions of linearity of the current-voltage relationship in ion-exchange membrane systems have been investigated using the network simulation method. A network model is proposed for the Nernst-Planck and Poisson equations describing the ionic transport through an ion-exchange membrane and the two diffusion boundary layers on both sides of the membrane. With this model and the electric circuit simulation program PSPICE(TM) , a decomposition into Fourier components of the electric current-time response, which follows the application of a sinusoidal-shaped electric potential, is obtained. The results reveal a considerable influence of the membrane fixed charge concentration on the amplitude of the different harmonics. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码：123 / 129
页数：7
相关论文
共 38 条
[21]   Using commercially available ion-exchange membranes to monitor plant-available nutrients in cranberry [J].
Davenport, Joan R. ;
Schiffhauer, Daniel E. .
COMMUNICATIONS IN SOIL SCIENCE AND PLANT ANALYSIS, 2007, 38 (9-10) :1331-1340
[22]   Mobility of Condensed Counterions in Ion-Exchange Membranes: Application of Screening Length Scaling Relationship in Highly Charged Environments [J].
Huang, Yuxuan ;
Fan, Hanqing ;
Yip, Ngai Yin .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2023, 58 (01) :836-846
[23]   Semi-interpenetrating networks (sIPN). Preparation of ion-exchange membranes, using a gaseous crosslinking reagent [J].
Metayer, M ;
MBareck, CO .
REACTIVE & FUNCTIONAL POLYMERS, 1997, 33 (2-3) :311-321
[24]   Estimation of the through-plane thermal conductivity of polymeric ion-exchange membranes using finite element technique [J].
Barragan, V. M. ;
Izquierdo-Gil, M. A. ;
Maroto, J. C. ;
Antoranz, P. ;
Munoz, S. .
INTERNATIONAL JOURNAL OF HEAT AND MASS TRANSFER, 2021, 176
[25]   Thermal Polymerization of Styrene Sorbed from the Gas Phase into Polymer Films as a Method for Synthesizing Precursors of Ion-Exchange Membranes [J].
A. N. Ponomarev ;
D. A. Kritskaya ;
E. F. Abdrashitov ;
V. Ch. Bokun ;
E. A. Sanginov ;
K. S. Novikova ;
Yu. A. Dobrovol’skii .
Russian Journal of Electrochemistry, 2019, 55 :738-744
[26]   Thermal Polymerization of Styrene Sorbed from the Gas Phase into Polymer Films as a Method for Synthesizing Precursors of Ion-Exchange Membranes [J].
Ponomarev, A. N. ;
Kritskaya, D. A. ;
Abdrashitov, E. F. ;
Bokun, V. Ch ;
Sanginov, E. A. ;
Novikova, K. S. ;
Dobrovol'skii, Yu A. .
RUSSIAN JOURNAL OF ELECTROCHEMISTRY, 2019, 55 (08) :738-744
[27]   Testing a simple Lee's disc method for estimating throuh-plane thermal conductivity of polymeric ion-exchange membranes [J].
Barragan, V. M. ;
Maroto, J. C. ;
Pastuschuk, E. ;
Munoz, S. .
INTERNATIONAL JOURNAL OF HEAT AND MASS TRANSFER, 2022, 184
[28]   A Study of Pore Formation and Methanol Vapor Permeability in Stretched Polytetrafluoroethylene Films Used as a Precursor of Composite Ion-Exchange Membranes [J].
Kritskaya, D. A. ;
Abdrashitov, E. F. ;
Bokun, V. Ch. ;
Ponomarev, A. N. .
PETROLEUM CHEMISTRY, 2018, 58 (04) :309-316
[29]   Permselectivity Study of Ion-Exchange Membranes in the Presence of Cu-HEDP Complexes from a Copper Plating Wastewater Treatment [J].
Jesus, J. M. S. ;
Scarazzato, T. ;
Tenorio, J. A. S. ;
Espinosa, D. C. R. .
APPLICATIONS OF PROCESS ENGINEERING PRINCIPLES IN MATERIALS PROCESSING, ENERGY AND ENVIRONMENTAL TECHNOLOGIES, 2017, :549-554
[30]   A Study of Pore Formation and Methanol Vapor Permeability in Stretched Polytetrafluoroethylene Films Used as a Precursor of Composite Ion-Exchange Membranes [J].
D. A. Kritskaya ;
E. F. Abdrashitov ;
V. Ch. Bokun ;
A. N. Ponomarev .
Petroleum Chemistry, 2018, 58 :309-316
1234