Transition-Metal-Catalyzed Electrophilic Amination: Application of O-Benzoylhydroxylamines in the Construction of the C-N Bond

被引：123
作者：
Dong, Xu [1 ]
Liu, Qing [1 ]
Dong, Yunhui [3 ]
Liu, Hui [1 ,2 ,3 ]
机构：
[1] Shandong Univ Technol, Sch Chem Engn, 266 West Xincun Rd, Zibo 255049, Peoples R China
[2] Hunan Univ, Coll Mat Sci & Engn, Changsha 410082, Hunan, Peoples R China
[3] Shandong Univ Technol, Engn Res Ctr Text Chem Dyeing & Finishing, Zibo 255049, Peoples R China
来源：
CHEMISTRY-A EUROPEAN JOURNAL | 2017年 / 23卷 / 11期
基金：
中国国家自然科学基金;
关键词：
cross-coupling; electrophilic amination; O-benzoylhydroxylamines; tertiary amines; transition-metal catalysis; EFFICIENT COPPER CATALYST; H AMINATION; INTERMOLECULAR AMINATION; ARYL HALIDES; BENZOYL HYDROXYLAMINES; CARBON-HETEROATOM; NATURAL-PRODUCTS; HYDROAMINATION; AMINES; PD;
D O I：
10.1002/chem.201601607
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Transition-metal-catalyzed electrophilic amination has been developed into a powerful tool for C-N bond construction. So far, O-benzoylhydroxylamines are the most widely used electrophilic aminating reagents. Herein, we summarize the recent advances of O-benzoylhydroxylamines involved in electrophilic amination catalyzed by transition metals. Several pioneering studies and some of the relevant mechanisms are discussed in this review.
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页码：2481 / 2511
页数：31
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