Relationship between the electrochemical and antioxidant activities of alkyl-substituted phenols

被引：6

作者：

Boiko, M. A. ^{[1
]}

Terakh, E. I. ^{[1
]}

Prosenko, A. E. ^{[1
]}

机构：

[1] Novosibirsk State Pedagog Univ, Res Inst Antioxidant Chem, Novosibirsk 630126, Russia

来源：

KINETICS AND CATALYSIS | 2006年 / 47卷 / 05期

关键词：

Induction Period; Oxidation Potential; Bond Dissociation Energy; Peroxy Radical; Phenoxyl;

D O I：

10.1134/S0023158406050041

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Oxidation potentials and rate constants have been determined for reactions between alkyl-substituted phenols with various structures and the styryl peroxy radical. The overall inhibiting activity of the phenols in the thermal autooxidation of lard has been studied. The interrelation between the structure, physicochemical properties, and antioxidant activity of the phenols is discussed.

引用

页码：677 / 681

页数：5

共 19 条

[1]

ABDULLAEVA FA, 1977, NEFTEKHIMIYA, V17, P931

[2]

[Anonymous], TORMOZHENIE PROTSESS, DOI DOI 10.1155/2013/602987

[3]

Baizer M., 1983, ORGANIC ELECTROCHEMI, V2nd

[4]

BILALOV SB, 1987, ZH ORG KHIM+, V23, P1508

[5]

Denisov ET, 1999, Handbook of antioxidants: Bond dissociation energies, rate constants, activation energies, and enthalpies of reactions, V2nd

[6]

GORBUNOV VN, 1981, KHIMIYA TEKHNOLOGIYA

[7]

KOZLIKOVSKII YB, 1984, ZH ORG KHIM, P121

[8]

KOZLIKOVSKII YB, 1978, IZV VYSSH UCHEBN ZAV, P648

[9]

Kuliev A.M, 1985, KHIMIYA TEKHNOLOGIYA, V2nd

[10] Substituted p-hydroquinones as a chain-breaking antioxidant during the oxidation of styrene [J].

Loshadkin, D ;

Roginsky, V ;

Pliss, E .

INTERNATIONAL JOURNAL OF CHEMICAL KINETICS, 2002, 34 (03) :162-171

← 1 2 →