Adsorption of Methyl Orange on Magnetically Separable Mesoporous Titania Nanocomposite

被引:14
作者
Gao, Libo [1 ,2 ]
Zhang, Qiang [1 ,2 ]
Li, Junyang [1 ,2 ]
Feng, Ruiting [1 ,2 ]
Xu, Hongyan [3 ]
Xue, Chenyang [1 ,2 ]
机构
[1] North Univ China, Minist Educ, Key Lab Instrumentat Sci & Dynam Measurement, Taiyuan 030051, Peoples R China
[2] North Univ China, Sci & Technol Elect Test & Measurement Lab, Taiyuan 030051, Peoples R China
[3] North Univ China, Sch Mat Sci & Engn, Taiyuan 030051, Peoples R China
基金
中国国家自然科学基金;
关键词
Mesoporous Fe3O4-SiO2-TiO2; Adsorption; Methyl orange; Pseudo-second order model; CORE-SHELL NANOCOMPOSITES; IRON-OXIDE NANOPARTICLES; PHOTOCATALYTIC DEGRADATION; TIO2; CRYSTALLINITY; MICROSPHERES; REMOVAL; CARBON; FILMS; DYES;
D O I
10.1016/j.cjche.2014.09.015
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The adsorption of mesoporous Fe3O4-SiO2-TiO2 (MFST), which can be separated easily from solution by a magnet, for the removal of methyl orange (MO) was investigated. The nitrogen adsorption-desorption measurement shows successful synthesis of MFST with an average pore size of 3.8 nm and a large specific surface area of 55 m(2).g(-1). About 95% adsorption percentage of MO is achieved with an initial concentration of 10 mg.L-1 in the dark and the MFST exhibits superior adsorption ability under acid conditions. The adsorption data fit well with the pseudo-second order model for adsorption. After 4 cycles, the adsorption rate for MO remains 74% in the dark and the MFST can be recovered in a magnetic field with a recovery of about 80 % (by mass). It demonstrates that the samples have significant value on applications of wastewater treatment. (C) 2014 The Chemical Industry and Engineering Society of China, and Chemical Industry Press. All rights reserved.
引用
收藏
页码:1168 / 1173
页数:6
相关论文
共 32 条
[1]   SYNTHESIS OF HEXAGONALLY PACKED MESOPOROUS TIO2 BY A MODIFIED SOL-GEL METHOD [J].
ANTONELLI, DM ;
YING, JY .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1995, 34 (18) :2014-2017
[2]   Photocatalytic degradation of X-3B by titania-coated magnetic activated carbon under UV and visible irradiation [J].
Ao, Yanhui ;
Xu, Jingjing ;
Fu, Degang ;
Yuan, Chunwei .
JOURNAL OF ALLOYS AND COMPOUNDS, 2009, 471 (1-2) :33-38
[3]   A simple method to prepare N-doped titania hollow spheres with high photocatalytic activity under visible light [J].
Ao, Yanhui ;
Xu, Jingjing ;
Fu, Degang ;
Yuan, Chunwei .
JOURNAL OF HAZARDOUS MATERIALS, 2009, 167 (1-3) :413-417
[4]   Adsorption of methyl orange and Cr(VI) on mesoporous TiO2 prepared by hydrothermal method [J].
Asuha, S. ;
Zhou, X. G. ;
Zhao, S. .
JOURNAL OF HAZARDOUS MATERIALS, 2010, 181 (1-3) :204-210
[5]   Mesoporous titanium phosphate molecular sieves with ion-exchange capacity [J].
Bhaumik, A ;
Inagaki, S .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (04) :691-696
[6]  
Chang J., 2013, CHINESE J CHEM ENG, V21, P1
[7]   Effective removal of high-chroma crystal violet over TiO2-based nanosheet by adsorption-photocatalytic degradation [J].
Chen, Feitai ;
Fang, Pengfei ;
Gao, Yuanpeng ;
Liu, Zhi ;
Liu, Yang ;
Dai, Yiqun .
CHEMICAL ENGINEERING JOURNAL, 2012, 204 :107-113
[8]   Discoloration and degradation of textile dye aqueous solutions with titanium oxide catalysts obtained by the sol-gel method [J].
Colpini, Leda Maria Saragiotto ;
Alves, Helton Jose ;
dos Santos, Onelia Aparecida Andreo ;
Costa, Creusa Maieru Macedo .
DYES AND PIGMENTS, 2008, 76 (02) :525-529
[9]   Synthesis and characterization of mesoporous titania microspheres and their applications [J].
Dwivedi, Charu ;
Raje, Naina ;
Nuwad, Jitendra ;
Kumar, Manmohan ;
Bajaj, Parma Nand .
CHEMICAL ENGINEERING JOURNAL, 2012, 193 :178-186
[10]   Adsorption of Pb, Cd, Cu, Zn, and Ni to titanium dioxide nanoparticles: effect of particle size, solid concentration, and exhaustion [J].
Engates, Karen E. ;
Shipley, Heather J. .
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH, 2011, 18 (03) :386-395