Electronic structures of highly deformed iron(III) porphyrin complexes

被引：162

作者：

Nakamura, Mikio ^{[1
]}

机构：

[1] Toho Univ, Sch Med, Dept Chem, Ota Ku, Tokyo 1438540, Japan

[2] Toho Univ, Grad Sch Sci, Div Chem, Funabashi, Chiba 2748510, Japan

[3] Toho Univ, Res Ctr Mat Integrated Properties, Funabashi, Chiba 2748510, Japan

来源：

COORDINATION CHEMISTRY REVIEWS | 2006年 / 250卷 / 17-18期

关键词：

porphyrin; iron(III); deformation; electronic structures; NMR; EPR; spin crossover;

D O I：

10.1016/j.ccr.2006.03.001

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

This review describes the effects of highly deformed porphyrin ring on the electronic structures of iron(III) porphyrinates, which includes (i) the electron configurations in low-spin (S = 1/2) ruffled complexes, (ii) the contribution of the intermediate-spin (S = 3/2) state in the spin-admixed (S = 5/2, 3/2) complexes with ruffled and saddled porphyrin ring, and (iii) the novel spin crossover (S = 1/2, S = 3/2) phenomenon in saddled complexes, with a special emphasis on the use of H-1 NMR, C-13 NMR, and EPR spectroscopy. (c) 2006 Elsevier B.V All rights reserved.

引用

页码：2271 / 2294

页数：24

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