Synthesis and characterization of imidocubanes with exocube GeIV and SnIV substituents:: [M(μ3-NGeMe3)]4 (M = Sn, Ge, Pb);: [Sn(μ3-NSnMe3)]4

被引：13

作者：

Eichler, Jack F. ^{[1
]}

Just, Oliver

Rees, William S., Jr.

机构：

[1] Emory Univ, Oxford Coll, Div Nat Sci & Math, Oxford, GA 30054 USA

[2] Oberlin Coll, Sch Chem & Biochem, Oberlin, OH 44074 USA

[3] Georgia Inst Technol, Sch Chem & Biochem, Atlanta, GA 30332 USA

[4] Georgia Inst Technol, Sch Mat Sci & Engn, Atlanta, GA 30332 USA

[5] Georgia Inst Technol, Mol Design Inst, Atlanta, GA 30332 USA

来源：

INORGANIC CHEMISTRY | 2006年 / 45卷 / 17期

关键词：

METAL AMIDES; TIN; COMPLEXES; PRECURSORS; NITROGEN; CUBANE;

D O I：

10.1021/ic060331y

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The heteroleptic lithium amide, [(Me3Sn)(Me3Ge)NLi.(Et2O)](2) (2), reacts with MCl2 (M = Sn, Ge, Pb) to yield the corresponding cubane complexes [M(mu(3)-NGeMe3)](4) [M = Sn (3), Ge (4), Pb (5)]. In an analogous reaction with SnCl2, the lithium stannylamide, [(Me3Sn)(2)NLi.(Et2O)](2) (1), produces the mixed-valent Sn congener [Sn(mu(3)-NSnMe3)](4) (6). All imidocubanes contain both di- and tetravalent group 14 metals that are bridged by N. These structures are comprised of M4N4 (M = Sn, Pb, Ge) cores that possess varying distortion from perfect cube geometry. The Pb derivative (5) exhibits enhanced volatility and vapor-phase integrity.

引用

页码：6706 / 6712

页数：7

共 32 条

[1] CRYSTAL AND MOLECULAR-STRUCTURES OF TETRAKIS(DIPHENYLKETIMINE) DERIVATIVES OF SILICON, GERMANIUM, AND TIN [J].

ALCOCK, NW ;

PIERCEBUTLER, M .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1975, (22) :2469-2476

[2] Reactions of group 14 metallocenes with lithiated primary amines;: alternative pathways in the formation of the primary tris(amido)stannate [(MANH)Sn(NHMA)2Li.2THF]1 and the cubanes [E(NCy)]4 (E=Sn2, Pb3; MA=(2-MeO)C6H4, Cy=C6H11) [J].

Allan, RE ;

Beswick, MA ;

Davies, MK ;

Raithby, PR ;

Steiner, A ;

Wright, DS .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1998, 550 (1-2) :71-76

[3] Association and fragmentation of imidotin(II) complexes containing donor-functionalised peripheries; towards new three-dimensional main group metal ligands [J].

Bashall, A ;

Feeder, N ;

Harron, EA ;

McPartlin, M ;

Mosquera, MEG ;

Sáez, D ;

Wright, DS .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2000, (22) :4104-4111

[4] The first mixed-valence fluorotin alkoxides:: New sol-gel precursors of fluorine-doped tin oxide materials [J].

Boegeat, D ;

Jousseaume, B ;

Toupance, T ;

Campet, G ;

Fournès, L .

INORGANIC CHEMISTRY, 2000, 39 (17) :3924-+

[5] The first structurally authenticated compound containing a bond between divalent tin and tetravalent tin [J].

Cardin, CJ ;

Cardin, DJ ;

Constantine, SP ;

Todd, AK ;

Teat, SJ ;

Coles, S .

ORGANOMETALLICS, 1998, 17 (11) :2144-2146

[6] SYNTHESIS AND STRUCTURAL AND SPECTROSCOPIC CHARACTERIZATION OF THE GERMANAZENE [GEN(2,6-I-PR2C6H3)]3 AND THE TIN AND LEAD TETRAMERS [SNN(BMES2)]4, [SNN(2,6-I-PR2C6H3)]4, AND [PBN(2,6-I-PR2C6H3)]4 [J].

CHEN, H ;

BARTLETT, RA ;

DIAS, HVR ;

OLMSTEAD, MM ;

POWER, PP .

INORGANIC CHEMISTRY, 1991, 30 (18) :3390-3394

[7] Formation of a dimeric sulfito-bridged imidotin cubane by oxidation of (SnNBut)4 with SO2 [J].

Chivers, T ;

Clark, TJ ;

Parvez, M ;

Schatte, G .

DALTON TRANSACTIONS, 2003, (11) :2107-2108

[8] Cubane complexes with two (or more) Group 14-Group 16 double bonds:: Synthesis and X-ray structures of Sn4Se2(NtBu)4 and Ge4Se3(NtBu)4 [J].

Chivers, T ;

Clark, TJ ;

Krahn, M ;

Parvez, M ;

Schatte, G .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2003, (10) :1857-1860

[9] Characterization of the sterically encumbered terphenyl-substituted species 2,6-Trip2H3C6Sn-Sn(Me)2C6H3-2,6-Trip2, an unsymmetric, group 14 element, methylmethylene, valence isomer of an alkene, its related lithium derivative 2,6-Trip2H3C6(Me)2Sn-Sn(Li)(Me)C6H3-2,6-Trip2, and the monomer Sn(t-Bu)C6H3-2,6-Trip2 (Trip = C6H2-2,4,6-i-Pr3) [J].

Eichler, BE ;

Power, PP .

INORGANIC CHEMISTRY, 2000, 39 (24) :5444-5449

[10] Solid-state and high-resolution liquid 119Sn NMR spectroscopy of some monomeric, two-coordinate low-valent tin compounds:: Very large chemical shift anisotropies [J].

Eichler, BE ;

Phillips, BL ;

Power, PP ;

Augustine, MP .

INORGANIC CHEMISTRY, 2000, 39 (24) :5450-5453

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