Electroactive D-A derivatives bearing 2,3-dimethylindole and tetrafluorostyrene moieties: Synthesis, polymerization, DFT calculations and photophysical properties

被引:0
|
作者
Eltan, T. [1 ,2 ]
Lapienyte, L. [2 ]
Keruckiene, R. [2 ]
Leitonas, K. [2 ]
Simokaitiene, J. [2 ]
Buika, G. [2 ]
Grazulevicius, J. V. [2 ]
机构
[1] Yalova Univ, Dept Polymer Engn, Bursa, Turkey
[2] Kaunas Univ Technol, Dept Polymer Chem & Technol, Kaunas, Lithuania
关键词
2; 3-dimethylindole; electroactive; tetrafluorostyrene; ionization potential; HOST MATERIALS; HIGHLY EFFICIENT; MECHANISM; BLUE;
D O I
10.1080/15421406.2018.1542082
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Two electroactive compounds, bearing 2,3-dimethylindole donor moiety and tetrafluorostyrene acceptor moiety, were designed and synthesized by employing one-step nucleophilic aromatic substitution reaction. Radical polymerization was used to obain electroactive linear polymer. Their photophysical properties, based on theoretical calculations and experimental measurements, as well as electrochemical and photoelectrical properties are discussed.
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页码:24 / 32
页数:9
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