A trinuclear double-helical metal complex of a quinquepyridine analog

被引：22

作者：

Baker, AT ^{[1
]}

Craig, DC ^{[1
]}

Dong, G ^{[1
]}

机构：

[1] UNIV NEW S WALES,SCH CHEM,SYDNEY,NSW 2052,AUSTRALIA

来源：

INORGANIC CHEMISTRY | 1996年 / 35卷 / 05期

关键词：

D O I：

10.1021/ic951372p

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A double-helical metal complex of an oligopyridine analog (i.e. with heterocycles other than pyridinyl rings) has been fully structurally characterized. This complex is the first example of a trinuclear double-helical complex containing quinquedentate and monodentate ligands and is of a type that has not been observed with the oligopyridines. In the rhetoric of metallosupramolecular chemistry much is said about the ''design'' of complexes of specific structure. Our work invites molecular engineers to consider pyrazolyl ligands as useful additions to their ''tool kit''.

引用

页码：1091 / &

页数：3

共 15 条

[1] MOLECULAR HELICITY IN INORGANIC COMPLEXES - DOUBLE HELICAL BINUCLEAR COMPLEXES OF 2,2'-6',2''-6'',2'''-6''',2''''-QUINQUEPYRIDINE (L) - CRYSTAL-STRUCTURES OF [CU2L2(O2CME)][PF6]3.H2O AND [CU2L2][PF6]3.2MECN
BARLEY, M
CONSTABLE, EC
CORR, SA
MCQUEEN, RCS
NUTKINS, JC
WARD, MD
DREW, MGB
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1988, (10): : 2655 - 2662
[2] MOLECULAR HELICITY IN INORGANIC COMPLEXES - BINUCLEAR AND TRINUCLEAR COMPLEXES OF 2,2'-6',2''-6'',2'''-6''',2''''-6'''',2'''''-SEXIPYRIDINE AND THE CRYSTAL AND MOLECULAR-STRUCTURE OF BIS(MU-2,2'-6',2''-6'',2'''-6''',2''''-6'''',2'''''-SEXIPYRIDINE-KAPPA-3N,N',N''-KAPPA-3N''',N'''',N''''')DICADMIUM HEXAFLUOROPHOSPHATE-ACETONITRILE (1/4)
CONSTABLE, EC
WARD, MD
TOCHER, DA
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1991, (07): : 1675 - 1683
[3] HIGHER OLIGOPYRIDINES AS A STRUCTURAL MOTIF IN METALLOSUPRAMOLECULAR CHEMISTRY
CONSTABLE, EC
[J]. PROGRESS IN INORGANIC CHEMISTRY, VOL 42, 1994, 42 : 67 - 138
[4] OLIGOPYRIDINES AS HELICATING LIGANDS
CONSTABLE, EC
[J]. TETRAHEDRON, 1992, 48 (46) : 10013 - 10059
[5] A DINUCLEATING QUINQUEPYRIDINE ANALOG
DONG, G
BAKER, AT
CRAIG, DC
[J]. INORGANICA CHIMICA ACTA, 1995, 231 (1-2) : 241 - 244
[6] GAL M, 1985, NOUV J CHIM, V9, P617
[7] HELICAL HEPTACOORDINATE COMPLEXES OF COBALT DERIVED FROM 2,2'-6',2''-6'',2'''-6''',2''''-QUINQUEPYRIDINE DERIVATIVES
GHEYSEN, KA
POTTS, KT
HURRELL, HC
ABRUNA, HD
[J]. INORGANIC CHEMISTRY, 1990, 29 (08) : 1589 - 1592
[8] 2,6-BIS(N-PYRAZOLYL)PYRIDINES - THE CONVENIENT SYNTHESIS OF A FAMILY OF PLANAR TRIDENTATE N3 LIGANDS THAT ARE TERPYRIDINE ANALOGS
JAMESON, DL
GOLDSBY, KA
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1990, 55 (17) : 4992 - 4994
[9] NOVEL 2 STEP SYNTHESIS OF PYRAZOLES AND ISOXAZOLES FROM ARYL METHYL KETONES
LIN, YI
LANG, SA
[J]. JOURNAL OF HETEROCYCLIC CHEMISTRY, 1977, 14 (02) : 345 - 347
[10] STRUCTURAL ASPECTS OF RED COPPER(I) COMPOUNDS
MELNIK, M
MACASKOVA, L
HOLLOWAY, CE
[J]. COORDINATION CHEMISTRY REVIEWS, 1993, 126 (1-2) : 71 - 92

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