Origin Traceability of Atractylodes Macrocephala Koidz. by Using Three-Way Fluorescence Coupled With Chemometrics

被引:3
作者
Chen Wei [1 ]
Wu Hai-long [1 ]
Wang Tong [1 ]
Chang Yue-yue [1 ]
Chen Yao [2 ]
Yang Jian [3 ]
Fu Hai-yan [4 ]
Yang Xiao-long [4 ]
Li Xu-fu [5 ]
Yu Ru-qin [1 ]
机构
[1] Hunan Univ, Coll Chem & Chem Engn, State Key Lab Chemo Biosensing & Chemometr, Changsha 410082, Peoples R China
[2] Hunan Univ Technol, Coll Life Sci & Chem, Hunan Key Lab Biomed Mat & Devices, Zhuzhou 412008, Peoples R China
[3] China Acad Chinese Med Sci, Natl Resource Ctr Chinese Mat Med, State Key Lab Breeding Base Dao Herbs, Beijing 100700, Peoples R China
[4] South Cent Univ Nationalities, Modernizat Engn Technol Res Ctr Ethn Minor Med Hu, Sch Pharmaceut Sci, Wuhan 430074, Peoples R China
[5] Beijing Tongrentang Pingjiang Atractylodes Macroc, Pingjiang 414500, Peoples R China
关键词
Atractylodes macrocephala Koidz; Chemometrics; Three-way fluorescence; Alternating trilinear decomposition; Origin traceability;
D O I
10.3964/j.issn.1000-0593(2022)09-2875-09
中图分类号
O433 [光谱学];
学科分类号
0703 ; 070302 ;
摘要
Atractylodes macrocephala Koidz. (AM) is a famous traditional Chinese medicine, the quality of AM is directly related to the producing area, so it is urgent to find a method to quickly identify the quality of AM and trace its origin. AM contains various endogenous fluorescent substances, which can provide a basis for identifying the origin of AM by three-way fluorescence technology. In this paper, the three-way fluorescence spectrum of AM was characterized by alternating trilinear decomposition (ATLD) and then three-way fluorescence was combined with partial least squares discriminant analysis (PLSDA) and k-Nearest Neighbors (kNN) to trace the origin of AM samples. The results show that the classification models established by PLS-DA and kNN could effectively distinguish samples from the three major AM production areas (Anhui, Hunan, and Zhejiang), and the classificationaccurate rate (CCR) of Zhejiang AM, a Dao-di AM herbs, is as high as 80 Yo and 90 in the prediction set, respectively. The proposed method provides a novel and rapid solution for the origin traceability of AM, which is conducive to maintaining the order of AM market and its industrial development.
引用
收藏
页码:2875 / 2883
页数:9
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