Atmospheric hydrodeoxygenation of bio-oil oxygenated model compounds: A review

被引：74

作者：

Pourzolfaghar, Hamed ^{[1
]}

Abnisa, Faisal ^{[1
]}

Daud, Wan Mohd Ashri Wan ^{[1
]}

Aroua, Mohamed Kheireddine ^{[2
,3
]}

机构：

[1] Univ Malaya, Fac Engn, Chem Engn Dept, Kuala Lumpur 50603, Malaysia

[2] Sunway Univ, Sch Sci & Technol, CCDCU, Bandar Sunway 47500, Petaling Jaya, Malaysia

[3] Univ Lancaster, Dept Engn, Lancaster LA1 4YW, England

来源：

JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS | 2018年 / 133卷

关键词：

Low pressure/atmospheric H-2; hydrodeoxygenation; Fast pyrolysis oil; Bio oil upgrading; Guaiacol; Phenolic compounds; VAPOR-PHASE HYDRODEOXYGENATION; BIOMASS FAST PYROLYSIS; GUAIACOL HYDRODEOXYGENATION; LIGNOCELLULOSIC BIOMASS; CATALYTIC CONVERSION; REACTION NETWORK; LOW-TEMPERATURE; AQUEOUS-PHASE; ACETIC-ACID; M-CRESOL;

D O I：

10.1016/j.jaap.2018.04.013

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Hydrodeoxygenation (HDO) of various bio oil oxygenated model compounds in low H-2 pressure has been discussed in this study. Because of the high yield of aromatic mixtures in bio-oil, they carry great potential for fuel efficiency. Nevertheless, due to its high viscosity, abundance of acid, and heteroatom contaminants, the bio-oil ought to be upgraded and hydrotreated in order to be applied as an alternative fuel. A continuous low H-2 pressure HDO of bio-oil is favored as it could be simply integrated with conventional pyrolysis systems, functioning at low pressures, as well as supporting a flexible plan for serial processing in respective bio-refineries. Additionally, such a process is cheaper and safer in comparison with the high pressure set ups. This review meticulously elaborates on the operation conditions, challenges, and opportunities for using this process in an industrial scale. The operating temperature, the H-2 flow ratio, the active site, and the catalyst stability are some important factors to be considered when it is intended to reach a high conversion efficiency for the HDO in low H-2 pressure.

引用

页码：117 / 127

页数：11

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