Electrochemical cross-coupling between functionalized aryl halides and 2-chloropyrimidine or 2-chloropyrazine catalyzed by nickel 2,2′-bipyridine complex

被引：58

作者：

Gosmini, C ^{[1
]}

Nédélec, JY ^{[1
]}

Périchon, J ^{[1
]}

机构：

[1] CNRS, Lab Electrochim Catalyse & Synth Organ, F-94320 Thiais, France

来源：

TETRAHEDRON LETTERS | 2000年 / 41卷 / 02期

关键词：

D O I：

10.1016/S0040-4039(99)02037-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

2-Arylpyrimidines and 2-arylpyrazines have been obtained in good to high yields from 2-chloropyrimidine and 2-chloropyrazine and various functionalized aryl halides by electroreduction using an iron rod as the anode and a catalytic amount of nickel-bipyridine complex in a mixture of DMF and pyridine as solvent. (C) 1999 Elsevier Science Ltd. All rights reserved.

引用

页码：201 / 203

页数：3

共 4 条

[1] Pyrolysis of 1-substituted pyrazoles and chloroform at 550°C:: formation of α-carboline from 1-benzylpyrazoles [J].

Bhatti, IA ;

Busby, RE ;

bin Mohamed, M ;

Parrick, J ;

Shaw, CJG .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1997, (24) :3581-3585

[2]

BOULTON AJ, 1984, COMPREHENSIVE HETERO, V2, P59

[3] Electrochemical cross-coupling between 2-halopyridines and aryl or heteroaryl halides catalysed by nickel-2,2′-bipyridine complexes. [J].

Gosmini, C ;

Lasry, S ;

Nedelec, JY ;

Perichon, J .

TETRAHEDRON, 1998, 54 (07) :1289-1298

[4] One-pot synthesis of 2-aryl- and 2-alkyl-pyrimidines [J].

Wang, TS ;

Cloudsdale, IS .

SYNTHETIC COMMUNICATIONS, 1997, 27 (14) :2521-2526

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