Biotransformation at 10 degrees C of di-n-butyl phthalate in subsurface microcosms

被引:15
作者
Chauret, C [1 ]
Inniss, WE [1 ]
Mayfield, CI [1 ]
机构
[1] UNIV WATERLOO,DEPT BIOL,WATERLOO,ON N2L 3G1,CANADA
关键词
D O I
10.1111/j.1745-6584.1996.tb02072.x
中图分类号
P [天文学、地球科学];
学科分类号
07 ;
摘要
Di-n-butyl phthalate (DBP) was found to be transformed by microorganisms under aerobic and anaerobic conditions at 10 degrees C in microcosms simulating the Canadian Forces Base (CFB) Borden subsurface environment. Biotransformation of DBP was observed under aerobic, nitrate-reducing, Fe(III)-reducing, and sulfate-reducing conditions. The biotransformation of DBP in the microcosms was significantly decreased as the redox potential was lowered, especially under sulfate-reducing conditions. However, other factors such as nutrient depletion and buildup of toxic intermediates could have affected the biotransformation rates. The highest DBP biotransformation rate (0.57 mu g DBP.g sediment(-1).day(-1)) was observed under aerobic conditions whereas the lowest rate (0.05 mu g DBP.g sediment(-1).day(-1)) was under sulfate-reducing conditions. Biotransformation of DBP at 10 degrees C was significantly enhanced by the addition of 10 mM NaNO3 suggesting that both the addition of nitrate and high redox conditions favor its biotransformation in subsurface environments.
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收藏
页码:791 / 794
页数:4
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