Electrochemically induced deposition of poly(benzoxazine) precursors as immobilization matrix for enzymes

被引：15

作者：

Andronescu, Corina ^{[1
]}

Poeller, Sascha ^{[2
]}

Schuhmann, Wolfgang ^{[2
]}

机构：

[1] Univ Politehn Bucuresti, Dept Bioresources & Polymer Sci, Bucharest 010072, Romania

[2] Ruhr Univ Bochum, D-44780 Bochum, Germany

来源：

ELECTROCHEMISTRY COMMUNICATIONS | 2014年 / 41卷

关键词：

Poly(benzoxazine); Electrodeposition; Amperometric biosensor; Enzyme immobilization; Potential pulse deposition; PERFORMANCE; FILMS;

D O I：

10.1016/j.elecom.2014.01.015

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Water-soluble benzoxazine oligomers were synthesized by reacting bisphenol A, tetraethylenepentamine and formaldehyde. The pre-formed benzoxazine oligomers can be further electropolymerized from aqueous suspensions under formation of poly(benzoxazine)-based films on electrode surfaces. Integration of glucose oxidase in a poly(benzoxazine) film let to highly reproducible and stable biosensors. Poly(benzoxazines) are proposed as a new family of stable polymers for the design of enzyme electrodes. (C) 2014 Elsevier B.V. All rights reserved.

引用

页码：12 / 15

页数：4

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