Copper-Catalyzed Double C-S Bonds Formation via Different Paths: Synthesis of Benzothiazoles from N-Benzyl-2-iodoaniline and Potassium Sulfide

被引：118

作者：

Zhang, Xiaoyun ^{[1
]}

Zeng, Weilan ^{[1
]}

Yang, Yuan ^{[1
]}

Huang, Hui ^{[1
]}

Liang, Yun ^{[1
,2
]}

机构：

[1] Hunan Normal Univ, Chem Biol & Tradit Chinese Med Res, Natl & Local Joint Engn Lab New Petrochem Mat & F, Minist Educ, Changsha 410081, Hunan, Peoples R China

[2] Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China

来源：

ORGANIC LETTERS | 2014年 / 16卷 / 03期

关键词：

HIGHLY EFFICIENT METHOD; ONE-POT SYNTHESIS; CARBON-SULFUR; ARYL HALIDES; SUBSTITUTED BENZOTHIAZOLES; COUPLING REACTIONS; 3-COMPONENT SYNTHESIS; PARALLEL SYNTHESIS; H BOND; THIOLS;

D O I：

10.1021/ol403638d

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new, highly efficient procedure for the synthesis of benzothiazoles from easily available N-benzyl-2-iodoaniline and potassium sulfide has been developed. The results show copper-catalyzed double C-S bond formation via a traditional cross-coupling reaction and an oxidative cross-coupling reaction.

引用

页码：876 / 879

页数：4

共 80 条

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