Bis(2,2′:6′,2"-terpyridine)cobalt(II) bis(tricyanomethanide)

被引：6

作者：

Luo, Jun ^{[1
]}

Zhang, Xin-Rong ^{[1
]}

Qiu, Li-Juan ^{[1
]}

Liu, Bao-Shu ^{[1
]}

Zhang, Zhi-Yan ^{[2
]}

机构：

[1] Second Mil Med Univ, Sch Pharm, Shanghai 200433, Peoples R China

[2] Second Mil Med Univ, Changhai Hosp, Dept Pharm, Shanghai 200433, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2009年 / 65卷

基金：

中国国家自然科学基金;

关键词：

CRYSTAL-STRUCTURE; TRICYANOMETHANIDE; C(CN)(3)(-); MAGNETISM; TCM(-);

D O I：

10.1107/S160053680901071X

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title complex, [Co(C15H11N3)(2)](C4N3)(2), is built up from discrete [Co(terpy)(2)](2+) cations (terpy is 2,2':6',2 ''-terpyridine) and [C(CN)(3)](-) anions. In the cation, the Co-II atom is coordinated by two terpy molecules, giving a distorted octahedral geometry. The tricyanomethanide anions are not directly coordinated to the Co-II atom, but some weak C-H center dot center dot center dot N hydrogen bonds involving the terminal N atoms of the tricyaomethanide ions and the terpyridine H atoms link anions and cations building a three-dimensional network.

引用

页码：M455 / U1027

页数：12

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