Study of Pd supported on Y or Ln containing ZrO2 as catalyst for the oxidation of hydrocarbons

被引：12

作者：

Zheng, Tingting ^{[1
]}

He, Junjun ^{[1
]}

Xia, Wenzheng ^{[1
]}

Hochstadt, Harold ^{[1
]}

Yang, Jiao ^{[1
]}

Zhao, Yunkun ^{[1
,2
]}

机构：

[1] Kunming Sino Platinum Met Catalysts Co Ltd, State Local Joint Engineer Lab Precious Met Catal, Kunming, Peoples R China

[2] Kunming Inst Precious Met, State Key Lab Adv Technol Comprehens Utilizat Pla, Kunming, Peoples R China

来源：

CATALYSIS COMMUNICATIONS | 2015年 / 71卷

基金：

中国国家自然科学基金;

关键词：

Yttrium-ZrO2; Ln-containing ZrO2; Palladium; Oxidation of hydrocarbons; EXHAUST-GAS TREATMENT; METHANE COMBUSTION; PALLADIUM CATALYSTS; PRETREATMENT CONDITIONS; ZIRCONIA CATALYSTS; PRECURSOR; OXIDES; OXYGEN;

D O I：

10.1016/j.catcom.2015.08.012

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A series of (Y, Ln = La, Ce, Pr, Nd)-containing ZrO2 mixed oxides was prepared by hydrothermal method, and the HC elimination was studied on Pd supported catalysts searching for explanation of the effects of Y and rare earth doping on the activity of catalyst. Of the catalysts examined, the activity of the Pd/Y-ZrO2 was better than other catalyst for the conversion of hydrocarbons. The properties of catalyst were assessed by BET, XRD, HRTEM, TPR and XPS measurements; the addition of La, Pr, Y to zirconium oxides resulted in enhanced thermal stability and promoted the stability of greater amounts of tetragonal ZrO2. (C) 2015 Elsevier B.V. All rights reserved.

引用

页码：51 / 55

页数：5

共 25 条

[1] Catalytic combustion of methane over palladium alumina modified by niobia [J].