Investigation of orthorhombic-to-tetragonal structural phase transition in (Ba1-xCax)(Zr0.05Ti0.95)O3 ferroelectric ceramics using micro-Raman scattering

被引：14
|
作者：
Singh, Gurvinderjit [1 ]
Sathe, Vasant [2 ]
Tiwari, V. S. [1 ]
机构：
[1] Raja Ramanna Ctr Adv Technol, Laser Mat Dev & Devices Div, Indore 452013, Madhya Pradesh, India
[2] UGC DAE Consortium Sci Res, Indore 452017, Madhya Pradesh, India
来源：
JOURNAL OF APPLIED PHYSICS | 2014年 / 115卷 / 04期
关键词：
BARIUM-TITANATE CERAMICS; LEAD-FREE CERAMICS; PIEZOELECTRIC PROPERTIES; BATIO3; DEPENDENCE; CRYSTALS; SPECTRUM;
D O I：
10.1063/1.4863303
中图分类号：
O59 [应用物理学];
学科分类号：
摘要：
Ferroelectric phase transition from orthorhombic-to-tetragonal phase was investigated in (Ba1-xCax)(Zr0.05Ti0.95)O-3 ceramics [x = 0.05, 0.08, 0.10] by micro-Raman scattering. The room temperature Raman scattering reveals the presence of orthorhombic-tetragonal phase co-existence by emergence of tetragonal phase with increase in calcium content. The temperature dependent Raman spectra also show similar cross-over with hardening of A(TO2) mode and disappearance of A(LO1) mode as system moves from orthorhombic-to-tetragonal phase. A thermal hysteresis of similar to 10K was observed in orthorhombic-to-tetragonal transition. (C) 2014 AIP Publishing LLC.
引用
收藏
页数：6
相关论文
共 29 条
  • [21] High piezoelectric d33 coefficient in (Ba1-xCax)(Ti0.98Zr0.02)O3 lead-free ceramics with relative high Curie temperature
    Li, Wei
    Xu, Zhijun
    Chu, Ruiqing
    Fu, Peng
    Zang, Guozhong
    MATERIALS LETTERS, 2010, 64 (21) : 2325 - 2327
  • [22] Pb-free (Ba1-xCax) (Zr0.18Ti0.82)O3 dielectric tunable ceramics with giant figure-of-merit under low electric field
    Xu, Kangli
    Yang, Pan
    Peng, Wei
    Li, Lingxia
    CERAMICS INTERNATIONAL, 2021, 47 (13) : 18037 - 18043
  • [23] Effect of processing conditions on (Ba1-xCax)(Ti0.9Sn0.1)O3 lead-free ceramics for the enhancement of structural, humidity sensing and dielectric properties
    Abd El-razek Mahmoud
    Ahmed S. Afify
    E. M. Saed
    M. K. Gergs
    Journal of the Australian Ceramic Society, 2019, 55 : 933 - 942
  • [24] Phase formation and piezoelectric properties of (Pb0.95Ba0.05)(Zr1-xTix)O3 ceramics fabricated by solid state reaction technique
    Kornphom, C.
    Panich, C.
    Bongkarn, T.
    MATERIALS RESEARCH INNOVATIONS, 2014, 18 : 146 - 150
  • [25] The crossover of (Ba1−xCax)(Ti0.9Sn0.1)O3 piezoelectric ceramics from single-phase to composite with studying the structural and dielectric properties
    Abd El-razek Mahmoud
    Ahmed S. Afify
    Amr Mohamed
    Journal of Materials Science: Materials in Electronics, 2017, 28 : 11591 - 11602
  • [26] PHASE TRANSITION AND ELECTRICAL PROPERTIES OF NEW LEAD-FREE (Na0.5K0.5)NbO3-Ba(Ti0.95Hf0.05)O3 SOLID SOLUTION CERAMICS
    Lv, Danya
    Zuo, Ruzhong
    Su, Shi
    Fu, Jian
    Liu, Yi
    CERAMICS-SILIKATY, 2011, 55 (02) : 101 - 105
  • [27] The effect of Barium substitution on the structural and dielectric properties of Pb1- XBaX(Zr0.52Ti0.43(Al0.5Sb0.5)0.05)O3 ceramics at the morphotropic phase boundary
    Benmakhlouf, A.
    Makhloufi, R.
    Boutarfaia, A.
    Messai, B.
    Hadji, F.
    Nouiri, M.
    JOURNAL OF OVONIC RESEARCH, 2023, 19 (03): : 295 - 305
  • [28] Piezoelectric properties of low-temperature sintered Pb0.95Ba0.05[(Mg1/3Nb2/3)0.125Zr0.445Ti0.43]O3 ceramics with chemically-added LiBiO2 sintering aid
    Hayashi, T
    Hasegawa, T
    JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2005, 25 (12) : 2437 - 2441
  • [29] Effect of addition of Ba(W0.5Cu0.5)O3 in Pb(Mg1/3Nb2/3)O3-Pb(Zn1/3Nb2/3)O3-Pb(Zr0.52Ti0.48)O3 ceramics on the sintering temperature, electrical properties and phase transition
    Chao, Xiaolian
    Yang, Zupei
    Xiong, Lirong
    Li, Zhao
    JOURNAL OF ALLOYS AND COMPOUNDS, 2011, 509 (02) : 512 - 517
123