Sugar-Functional Vinyl Addition Poly(norbornene)-Photopatternable Poly(norbornenyl gluconamide) Compositions Developed with Water

被引：5

作者：

Smith, Steven ^{[1
,2
]}

Paudel, Liladhar ^{[1
]}

Cyrus, Crystal ^{[1
,4
]}

Burgoon, Hugh ^{[1
]}

Fujita, Kazuyoshi ^{[1
,3
]}

Thoresen, Jennifer ^{[1
]}

Thomas, Kim ^{[1
]}

Langsdorf, Leah ^{[1
]}

Rhodes, Larry F. ^{[1
]}

机构：

[1] Promerus LLC, 9921 Brecksville Rd, Brecksville, OH 44141 USA

[2] Gabriel Performance Prod, Res, 725 State Rd, Ashtabula, OH 44004 USA

[3] Sumitomo Bakelite Co Ltd, Shinagawa Ku, 5-8 Higashi Shinagawa 2 Chome, Tokyo 1400002, Japan

[4] Lubrizol Corp, 9911 Brecksville Rd, Brecksville, OH 44141 USA

来源：

ACS OMEGA | 2018年 / 3卷 / 03期

关键词：

PHOSPHINE CARBOXYLATE COMPLEXES; CORRELATION NMR-SPECTROSCOPY; INSERTION POLYMERIZATION; NORBORNENE; RESOLUTION; PDCL2(TPPTS)(2); PHOTORESISTS; DERIVATIVES; COPOLYMERS; CATALYSTS;

D O I：

10.1021/acsomega.8b00081

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The norbornenyl gluconamide (NBGA) monomer can be polymerized by a number of palladium catalysts to give water-soluble, vinyl addition poly(NBGA). Depending on the catalyst used, the reaction conditions, and the chain-transfer additives employed, high-molecular-weight polymers can be obtained. These polymers can be thermally cross-linked at ca. 190 degrees C or at ca. 150 degrees C when the difunctional glutaraldehyde is added. A photopatternable composition is formed by the addition of a water-soluble diazide when the poly(NBGA) molecular weight is sufficiently high. After image-wise exposure, negative-tone patterns are revealed by water development. A detailed analysis of NBGA monomer structures by high-resolution nuclear magnetic resonance techniques including pure shift is reported showing that two diastereomers of each endo-and exo-isomer are formed from the reaction of norbornene methylamine and delta-gluconolactone.

引用

页码：2909 / 2917

页数：9

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