Catalytic Staudinger-Vilarrasa Reaction for the Direct Ligation of Carboxylic Acids and Azides

被引：65

作者：

Bures, Jordi ^{[1
]}

Martin, Manuel ^{[1
]}

Urpi, Felix ^{[1
]}

Vilarrasa, Jaume ^{[1
]}

机构：

[1] Univ Barcelona, Dept Quim Organ, Fac Quim, E-08028 Barcelona, Catalonia, Spain

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2009年 / 74卷 / 05期

关键词：

NATIVE CHEMICAL LIGATION; OXIDATION-REDUCTION CONDENSATION; AZA-WITTIG REACTION; ONE-POT PREPARATION; 2 REDOX REACTIONS; PEPTIDE SYNTHESIS; SYNTHETIC TRICKS; NATURAL-PRODUCTS; PUROMYCIN ANALOGS; GLYCOSYL AZIDES;

D O I：

10.1021/jo802825e

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

2,2'-Dipyridyl diselenide (PySeSePy) is the catalyst or activator of choice for the direct reaction of carboxylic acids with azides and trimethylphosphine at room temperature. The mechanism of the process, which is not an aza-Wittig reaction, has been elucidated.

引用

页码：2203 / 2206

页数：4

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